Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts
文献类型：期刊论文
| 作者 | Liu, Huijuan1,2; Zhang, Ling1,2; Li, Xiujie1; Huang, Shengjun1; Liu, Shenglin1; Xin, Wenjie1; Xie, Sujuan1; Xu, Longya1 |
| 刊名 | journal of natural gas chemistry
 |
| 出版日期 | 2009-09-01 |
| 卷号 | 18期号:3页码:331-336 |
| 关键词 | propene 1-butene metathesis 10WO(3)/Al(2)O(3)-xHY bifunction |
| 英文摘要 | a new propene production route from 1-butene metathesis has been developed on heterogeneous 10wo(3)/al(2)o(3)-hy catalysts with different hy contents. it is found that the catalysts play bi-functionally first for the isomerization of i-butene to 2-butene and then for the cross-metathesis between 1-butene and 2-butene to propene and 2-pentene. the combination of hy zeolite and al(2)o(3) is prerequisite for the production of propene. the propene yield keeps increasing with the hy content in the range of 10-70 wt%, where 10wo(3)/al(2)o(3)-70hy exhibits the highest propene yield. the ms-h(2)-tpr and ms-o(2)-tpo characterizations indicate that the increase of hy content in the catalysts weakens the interaction between w species and supports, whereas enhance the probability of coking on the metal species and acid sites. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical |
| 研究领域[WOS] | chemistry ; energy & fuels ; engineering |
| 关键词[WOS] | 2-butene ; ethene ; isomerization ; alumina |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000271072500012 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141591]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Huijuan,Zhang, Ling,Li, Xiujie,et al. Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts[J]. journal of natural gas chemistry,2009,18(3):331-336. |
| APA | Liu, Huijuan.,Zhang, Ling.,Li, Xiujie.,Huang, Shengjun.,Liu, Shenglin.,...&Xu, Longya.(2009).Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts.journal of natural gas chemistry,18(3),331-336. |
| MLA | Liu, Huijuan,et al."Production of propene from 1-butene metathesis reaction on tungsten based heterogeneous catalysts".journal of natural gas chemistry 18.3(2009):331-336. |
入库方式： OAI收割
来源：大连化学物理研究所
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