Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive
文献类型：期刊论文
| 作者 | Li, Wei1; Liu, Han1; Du, Da-Ming1,2 |
| 刊名 | synlett
 |
| 出版日期 | 2009-04-01 |
| 期号 | 6页码:925-928 |
| 关键词 | Michael addition nitroalkene catalysis amino acids DBU |
| 英文摘要 | a mild michael addition of glycine imines to aromatic-nitroalkenes catalyzed by 10 mol% dbu with liotf as an additive was developed. in most cases, the products could be obtained in good yields (up to 96%) with moderate to good diastereoselectivities (up to 10:1). the selectivity for syn adduct can be reversed to anti when the r group of glycine imines was changed from methyl or ethyl to tert-butyl. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | phase-transfer catalysis ; alpha-amino-acids ; friedel-crafts alkylation ; enantioselective synthesis ; azomethine ylides ; ethyl n-(diphenylmethylene)glycinate ; 1,3-dipolar cycloaddition ; derivatives ; complexes ; bis(oxazoline) |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000266069100008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141608]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Peking Univ, Coll Chem & Mol Engn, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Beijing 100871, Peoples R China 2.Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Wei,Liu, Han,Du, Da-Ming. Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive[J]. synlett,2009(6):925-928. |
| APA | Li, Wei,Liu, Han,&Du, Da-Ming.(2009).Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive.synlett(6),925-928. |
| MLA | Li, Wei,et al."Mild Michael Addition of Glycine Imines to Aromatic Nitroalkenes Catalyzed by DBU with LiOTf as an Additive".synlett .6(2009):925-928. |
入库方式： OAI收割
来源：大连化学物理研究所
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