A Mechanically Interlocked [3]Rotaxane as a Light-Harvesting Antenna: Synthesis, Characterization, and Intramolecular Energy Transfer
文献类型：期刊论文
| 作者 | Wang, Jie-Yu1,2; Han, Ji-Min1,2; Yan, Jing1,2; Ma, Yuguo1,2; Pei, Jian1,2 |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2009 |
| 卷号 | 15期号:14页码:3585-3594 |
| 关键词 | aggregation click chemistry cycloaddition energy transfer molecular devices oligo(phenylenevinylene) |
| 英文摘要 | a mechanically interlocked light-harvesting system [3]rotaxane a has been synthesized in high yield through cu(i)-catalyzed azide-alkyne cycloaddition; the hexyl-substituted truxene units are introduced into the wheels as donors and an oligo(paraphenylenevinylene) (opv) unit into the axis as the acceptor. the structure and the purity of [3]rotaxane a were confirmed by (1)h and (13)c nmr spectroscopy and esi hrms. the azide-alkyne cycloaddition is demonstrated to be an efficient stoppering method in the synthesis of the rotaxane containing dibenzo[24]crown-8 and dibenzyl ammonium units. detailed steady-state uv/vis absorption, photoluminescent, and time-resolved fluorescence spectroscopy were performed to investigate the photophysical properties of [3]rotaxane a and its reference compounds in solution and as thin films. even in dilute solution, efficient energy transfer from the truxene-functionalized wheels to the opv-based axis, through the dibenzo[24]crown-8 and dibenzyl ammonium interaction, is observed in [3]rotaxane a. the unique topology of [3]rotaxane a not only efficiently promotes the intramolecular energy-transfer process, but also prevents intermolecular aggregation in the solid state. the new antenna system opens up the possibility of controllable light-harvesting molecular machines or other optoelectronic devices on the nanometer scale. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | unsymmetrical conjugated dendrimers ; stiff dendritic macromolecules ; electron-transfer processes ; charge-separated-state ; photophysical properties ; alpha-cyclodextrin ; shape-persistent ; click-chemistry ; supramolecular chemistry ; rotaxane structures |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000264774400031 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141619]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China 2.Peking Univ, Minist Educ, Coll Chem, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jie-Yu,Han, Ji-Min,Yan, Jing,et al. A Mechanically Interlocked [3]Rotaxane as a Light-Harvesting Antenna: Synthesis, Characterization, and Intramolecular Energy Transfer[J]. chemistry-a european journal,2009,15(14):3585-3594. |
| APA | Wang, Jie-Yu,Han, Ji-Min,Yan, Jing,Ma, Yuguo,&Pei, Jian.(2009).A Mechanically Interlocked [3]Rotaxane as a Light-Harvesting Antenna: Synthesis, Characterization, and Intramolecular Energy Transfer.chemistry-a european journal,15(14),3585-3594. |
| MLA | Wang, Jie-Yu,et al."A Mechanically Interlocked [3]Rotaxane as a Light-Harvesting Antenna: Synthesis, Characterization, and Intramolecular Energy Transfer".chemistry-a european journal 15.14(2009):3585-3594. |
入库方式： OAI收割
来源：大连化学物理研究所
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