Dynamic Characterization of Graphene Growth and Etching by Oxygen on Ru(0001) by Photoemission Electron Microscopy
文献类型:期刊论文
作者 | Cui, Yi; Fu, Qiang; Zhang, Hui; Tan, Dali; Bao, Xinhe |
刊名 | journal of physical chemistry c |
出版日期 | 2009-11-26 |
卷号 | 113期号:47页码:20365-20370 |
英文摘要 | epitaxial growth of graphene on ru(0001) was investigated by photoemission electron microscopy (peem) and scanning tunneling microscopy (stm). by connecting the mesoscopic length scale of peem and the microscopic length scale of stm, we show that graphene overlayers with sizes ranging from nanometers to sub-millimeters have been prepared on ru(0001) in a well-controllable fashion. from the systematic investigation of different methods to grow graphene on ru(0001), the dominant factors in the graphene growth process have been revealed, which enables to grow graphene on transition metal surfaces in a controllable way. additionally, the dynamic process of graphene etching by oxygen at temperatures between 600-1000 k was studied by in situ peem. the reaction kinetics results show that decrease in the graphene overlayers size is linearly dependent on the reaction time, indicating a reaction-controlled process. the catalytic effect of ru substrate facilitates graphene oxidation, which shows relatively low activation energy of 27.2 kj/mol. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
关键词[WOS] | chemical-vapor-deposition ; graphite monolayer ; carbon-films ; pt(111) ; intercalation ; ni(111) ; oxidation ; kinetics ; dispersions ; catalysts |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000271826100035 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141622] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, State Key Laboratoty Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Cui, Yi,Fu, Qiang,Zhang, Hui,et al. Dynamic Characterization of Graphene Growth and Etching by Oxygen on Ru(0001) by Photoemission Electron Microscopy[J]. journal of physical chemistry c,2009,113(47):20365-20370. |
APA | Cui, Yi,Fu, Qiang,Zhang, Hui,Tan, Dali,&Bao, Xinhe.(2009).Dynamic Characterization of Graphene Growth and Etching by Oxygen on Ru(0001) by Photoemission Electron Microscopy.journal of physical chemistry c,113(47),20365-20370. |
MLA | Cui, Yi,et al."Dynamic Characterization of Graphene Growth and Etching by Oxygen on Ru(0001) by Photoemission Electron Microscopy".journal of physical chemistry c 113.47(2009):20365-20370. |
入库方式: OAI收割
来源:大连化学物理研究所
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