Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran
文献类型：期刊论文
| 作者 | Jiao, Lei; Lin, Mu; Zhuo, Lian-Gang; Yu, Zhi-Xiang |
| 刊名 | organic letters
 |
| 出版日期 | 2010-06-04 |
| 卷号 | 12期号:11页码:2528-2531 |
| 英文摘要 | a novel rh(i)-catalyzed [(3 + 2) + 1] cycloaddition, which can be regarded as a homologous pauson-khand reaction, was developed to synthesize bicyclic cyclohexenones and cyclohexanones, enabling a new approach for synthesis of six-membered carbocycles ubiquitously found in natural products and pharmaceutics. the significance of the rh-catalyzed [(3 + 2) + 1] cycloaddition has been demonstrated by the total synthesis of a furanoid sesquiterpene natural product, a-agarofuran, in which the bicyclic skeleton was constructed by the [(3 + 2) + 1] reaction of 1-yne-vcp and co. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | diels-alder reactions ; donor-acceptor cyclopropanes ; alpha-agarofuran ; ene-vinylcyclopropanes ; beta-agarofuran ; mechanism ; alkynes ; sesquiterpenoids ; 1,3-dienes ; aldehydes |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000278062600023 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141653]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Peking Univ, BNLMS, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiao, Lei,Lin, Mu,Zhuo, Lian-Gang,et al. Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran[J]. organic letters,2010,12(11):2528-2531. |
| APA | Jiao, Lei,Lin, Mu,Zhuo, Lian-Gang,&Yu, Zhi-Xiang.(2010).Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran.organic letters,12(11),2528-2531. |
| MLA | Jiao, Lei,et al."Rh(I)-Catalyzed [(3+2)+1] Cycloaddition of 1-Yne/Ene-vinylcyclopropanes and CO: Homologous Pauson-Khand Reaction and Total Synthesis of (+/-)-alpha-Agarofuran".organic letters 12.11(2010):2528-2531. |
入库方式： OAI收割
来源：大连化学物理研究所
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