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Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [EMINI][TCB] using gas-liquid chromatography

文献类型:期刊论文

作者Yan, Pei-Fang1; Yang, Miao1; Liu, Xiu-Mei1; Wang, Chang1; Tan, Zhi-Cheng1,2; Welz-Biermann, Urs1
刊名journal of chemical thermodynamics
出版日期2010-06-01
卷号42期号:6页码:817-822
关键词Ionic liquid Gas-liquid chromatography Activity coefficient at infinite dilution Partial molar excess enthalpy at infinite dilution
英文摘要the activity coefficients at infinite dilution, gamma(infinity)(i), for both polar and non-polar solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [emim][tcb] have been determined by gas liquid chromatography at the temperatures from (303 to 343) k. the partial molar excess enthalpies at infinite dilution of the h(i)(e,infinity) solutes in the ionic liquid were also calculated from the temperature dependence of the gamma(infinity)(i) values. the selectivity for the hexane/benzene and cyclohexane/benzene separation problems was calculated from experimental infinite dilution activity coefficient values and compared to the other ionic liquids, taken from the recent literature. (c) 2010 elsevier ltd. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]thermodynamics ; chemistry, physical
研究领域[WOS]thermodynamics ; chemistry
关键词[WOS]sensitized solar-cells ; thermodynamic properties ; virial coefficients ; nonpolar solutes ; alkyl benzenes ; polar solutes ; mixtures ; hydrocarbons ; alcohols ; aldehydes
收录类别SCI
语种英语
WOS记录号WOS:000277647000019
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/141663]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Yan, Pei-Fang,Yang, Miao,Liu, Xiu-Mei,et al. Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [EMINI][TCB] using gas-liquid chromatography[J]. journal of chemical thermodynamics,2010,42(6):817-822.
APA Yan, Pei-Fang,Yang, Miao,Liu, Xiu-Mei,Wang, Chang,Tan, Zhi-Cheng,&Welz-Biermann, Urs.(2010).Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [EMINI][TCB] using gas-liquid chromatography.journal of chemical thermodynamics,42(6),817-822.
MLA Yan, Pei-Fang,et al."Activity coefficients at infinite dilution of organic solutes in the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate [EMINI][TCB] using gas-liquid chromatography".journal of chemical thermodynamics 42.6(2010):817-822.

入库方式: OAI收割

来源:大连化学物理研究所

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