Bi4Cu0.2V1.8O11-delta based electrolyte membrane reactor for selective oxidation of propane to acrylic acid
文献类型：期刊论文
| 作者 | Wang, Jibo1,2; Ji, Baofeng1,2; Chu, Wenling1; Zhan, Shijing1,2; Lin, Liwu1; Yang, Weishen1 |
| 刊名 | catalysis today
 |
| 出版日期 | 2010-01-15 |
| 卷号 | 149期号:1-2页码:157-162 |
| 关键词 | Solid electrolyte membrane reactor Oxygen permeable membrane Selective oxidation Propane Acrylic acid |
| 英文摘要 | an electrochemical membrane reactor using bi4cu0.2v1.8o11-delta as a solid electrolyte membrane was employed to investigate the selective oxidation of propane to acrylic acid over a mov0.3te0.17nb0.12o catalyst. by applying an external current to the membrane reactor, the ionic oxygen was pumped to the surface of the mov0.3te0.17nb0.12o catalyst, which exhibited higher conversion of propane and selectivity to acrylic acid than that in the fixed-bed reactor. the results indicate that the enhancement of catalytic performance in the membrane reactor is mainly due to the presence of the lattice oxygen, which has been proved to be necessary for the formation of acrylic acid. thus, the au/bi4cu0.2v1.8o11-delta/au/movtenbo membrane reactor achieved a higher conversion of propane (42%) and selectivity to acrylic acid (79.6%) at 380 degrees c with a 0.6 a current. (c) 2009 elsevier b.v. all rights reserved |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | oxide-ion conductors ; oxygen ; catalysts ; dehydrogenation ; hydrocarbons ; performance ; bi4v2o11 ; ethane ; system ; phase |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000274145600025 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141676]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Jibo,Ji, Baofeng,Chu, Wenling,et al. Bi4Cu0.2V1.8O11-delta based electrolyte membrane reactor for selective oxidation of propane to acrylic acid[J]. catalysis today,2010,149(1-2):157-162. |
| APA | Wang, Jibo,Ji, Baofeng,Chu, Wenling,Zhan, Shijing,Lin, Liwu,&Yang, Weishen.(2010).Bi4Cu0.2V1.8O11-delta based electrolyte membrane reactor for selective oxidation of propane to acrylic acid.catalysis today,149(1-2),157-162. |
| MLA | Wang, Jibo,et al."Bi4Cu0.2V1.8O11-delta based electrolyte membrane reactor for selective oxidation of propane to acrylic acid".catalysis today 149.1-2(2010):157-162. |
入库方式： OAI收割
来源：大连化学物理研究所
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