Synthesis and Crystal Structure of Nickle 3,5-Pyridinedicarboxylates
文献类型：期刊论文
| 作者 | Jin Qiang1; Zhao Jiao2; Shi Xin1 |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2010-08-10 |
| 卷号 | 31期号:8页码:1496-1501 |
| 关键词 | Coordination polymer 3 Crystal structure 5-Pyridinedicarboxylic acid |
| 英文摘要 | three new nickle 3,5-pyridinedicarboxylates coordination polymers, [ni (3,5-pydc) (h2o)(4)center dot h2o](n) (1), [ni-2 (3, 5-pydc)(2) (h2o)(8)center dot (h2o)(2)](n) (2) and [ni (3,5-pydc) (h2o)(2)](n) (3) were synthesized by hydrothermal method and characterized by single-crystal x-ray diffraction, ftir and tga. x-ray crystallography reveals that both complexes 1 and 2 are 1d zigzag chains, while complex 3 is a 2d layered network. in complex 1, 3,5-pydc ligand links two different ni(ii) into 1d zigzag chain. there are two independent 1d zigzag chains with same coordination mode in complex 2 and each zigzag chain is formed by 3,5-pydc ligand connecting with ni(ii). complex 3 is a 2d network constructed by twenty-membered rings comprising three ni (ii) and three 3,5-pydc ligands. furthermore, three compounds form 3d supramolecular frameworks through o-h center dot center dot center dot o hydrogen bonds among chains or layers. the guest water molecules are defined in supramolecular frameworks of complexes 1 and 2. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | coordination polymers ; hydrothermal synthesis ; complex ; acid ; pyridine-3,5-dicarboxylate |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000281590200004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141718]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Normal Univ, Inst Chem Functionalized Mat, Dept Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin Qiang,Zhao Jiao,Shi Xin. Synthesis and Crystal Structure of Nickle 3,5-Pyridinedicarboxylates[J]. chemical journal of chinese universities-chinese,2010,31(8):1496-1501. |
| APA | Jin Qiang,Zhao Jiao,&Shi Xin.(2010).Synthesis and Crystal Structure of Nickle 3,5-Pyridinedicarboxylates.chemical journal of chinese universities-chinese,31(8),1496-1501. |
| MLA | Jin Qiang,et al."Synthesis and Crystal Structure of Nickle 3,5-Pyridinedicarboxylates".chemical journal of chinese universities-chinese 31.8(2010):1496-1501. |
入库方式： OAI收割
来源：大连化学物理研究所
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