Cooperative structure-directing effect in the synthesis of aluminophosphate molecular sieves in ionic liquids
文献类型：期刊论文
| 作者 | Xu, Renshun1; Shi, Xiaochao2; Zhang, Weiping1; Xu, Yunpeng1; Tian, Zhijian1; Lu, Xiaobing2; Han, Xiuwen1; Bao, Xinhe1 |
| 刊名 | physical chemistry chemical physics
 |
| 出版日期 | 2010 |
| 卷号 | 12期号:10页码:2443-2449 |
| 英文摘要 | in situ two-dimensional nmr and fluorescence emission spectroscopy were employed to investigate the cooperative structure-direction effect of organic amine such as morpholine in the synthesis of aluminophosphate molecular sieves in ionic liquids. in situ rotating frame nuclear overhauser effect spectra (roesy) together with fluorescence measurements demonstrate that the aggregates between imidazolium cations and morpholines through intermolecular hydrogen bonds can be formed in the gel during the crystallization of molecular sieves. combining with the characterizations of the solid products by solid-state nmr, it is verified that different aggregates of organic amines with imidazolium cations, which is similar to self-assembled supramolecular analogues, could act as the structure-directing agents for selective tuning of the framework topologies such as ael, afi and lta in the final solid products. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | ionothermal synthesis ; fluorescence behavior ; zeolite ; nmr ; crystallization ; template ; agents ; derivatives ; frameworks ; chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000274920200020 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141741]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Renshun,Shi, Xiaochao,Zhang, Weiping,et al. Cooperative structure-directing effect in the synthesis of aluminophosphate molecular sieves in ionic liquids[J]. physical chemistry chemical physics,2010,12(10):2443-2449. |
| APA | Xu, Renshun.,Shi, Xiaochao.,Zhang, Weiping.,Xu, Yunpeng.,Tian, Zhijian.,...&Bao, Xinhe.(2010).Cooperative structure-directing effect in the synthesis of aluminophosphate molecular sieves in ionic liquids.physical chemistry chemical physics,12(10),2443-2449. |
| MLA | Xu, Renshun,et al."Cooperative structure-directing effect in the synthesis of aluminophosphate molecular sieves in ionic liquids".physical chemistry chemical physics 12.10(2010):2443-2449. |
入库方式： OAI收割
来源：大连化学物理研究所
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