Transfer Dehydrogenation of 1-Octanol to 1-Octanal over Cu/MgO Catalyst: Effect of Cu Particle Size
文献类型：期刊论文
| 作者 | Shi Ruijuan; Wang Fei; Mu Xiaoling; Ta Na; Li Yong; Huang Xiumin; Shen Wenjie |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2010-06-01 |
| 卷号 | 31期号:6页码:626-630 |
| 关键词 | copper magnesia particle size transfer dehydrogenation 1-octanol 1-octanal |
| 英文摘要 | cu/mgo catalysts with different cu particle sizes were prepared by a precipitation-deposition method and investigated for their activity in the transfer dehydrogenation of alcohols to carbonyl compounds. they were highly active for the conversion of primary aliphatic alcohols, e.g. 1-octanol. with increasing cu particle size from 4.6 to 7.4 nm, the aldehyde yield decreased from 65% 10 55%, which showed a size effect. the copper particle abstracted an alpha-hydrogen from the reactive alkoxide intermediate formed on the surface of mgo and simultaneously catalyzed the hydrogenation of styrene. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | environmentally benign oxidation ; free alcohol dehydrogenation ; secondary alcohols ; palladium ; hydrotalcite ; cu/al2o3 ; acceptor ; oxides |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000279808000005 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141745]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi Ruijuan,Wang Fei,Mu Xiaoling,et al. Transfer Dehydrogenation of 1-Octanol to 1-Octanal over Cu/MgO Catalyst: Effect of Cu Particle Size[J]. chinese journal of catalysis,2010,31(6):626-630. |
| APA | Shi Ruijuan.,Wang Fei.,Mu Xiaoling.,Ta Na.,Li Yong.,...&Shen Wenjie.(2010).Transfer Dehydrogenation of 1-Octanol to 1-Octanal over Cu/MgO Catalyst: Effect of Cu Particle Size.chinese journal of catalysis,31(6),626-630. |
| MLA | Shi Ruijuan,et al."Transfer Dehydrogenation of 1-Octanol to 1-Octanal over Cu/MgO Catalyst: Effect of Cu Particle Size".chinese journal of catalysis 31.6(2010):626-630. |
入库方式： OAI收割
来源：大连化学物理研究所
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