Crossed Beams Study on the Dynamics of the F-Atom Reaction with Ammonia
文献类型：期刊论文
| 作者 | Xiao, Chongfa; Shen, Guanlin; Wang, Xiuyan; Fan, Hongjun; Yang, Xueming |
| 刊名 | journal of physical chemistry a
 |
| 出版日期 | 2010-04-08 |
| 卷号 | 114期号:13页码:4520-4523 |
| 英文摘要 | the f-atom reaction with nh(3) and nd(3) has been studied using the universal crossed beams technique. angular resolved time-of-flight spectra were measured for the hf and df reaction products. product angular distribution and product kinetic energy distribution in the center-of-mass frame were determined from the experimental tof spectra. experimental results show that the hf and df products are largely forward-scattered relative to the f-atom beam direction with a considerable amount of product at sideway and backward scattering directions. high-level ab initio calculation on the reaction energy pathway suggests that the forward-scattered products are mainly produced via a direct abstraction mechanism at large impact parameters, whereas sideway- and backward-scattered products are likely due to a long-lived complex formation mechanism. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | molecular-beam ; f+cd4 reaction ; scattering ; resonances ; section |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000276096800006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141775]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Chongfa,Shen, Guanlin,Wang, Xiuyan,et al. Crossed Beams Study on the Dynamics of the F-Atom Reaction with Ammonia[J]. journal of physical chemistry a,2010,114(13):4520-4523. |
| APA | Xiao, Chongfa,Shen, Guanlin,Wang, Xiuyan,Fan, Hongjun,&Yang, Xueming.(2010).Crossed Beams Study on the Dynamics of the F-Atom Reaction with Ammonia.journal of physical chemistry a,114(13),4520-4523. |
| MLA | Xiao, Chongfa,et al."Crossed Beams Study on the Dynamics of the F-Atom Reaction with Ammonia".journal of physical chemistry a 114.13(2010):4520-4523. |
入库方式： OAI收割
来源：大连化学物理研究所
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