Au/Mg(OH)(2): Highly efficient for selective oxidation of 1,2-propanediol to lactic acid with molecular oxygen
文献类型:期刊论文
作者 | Ma Hong1; Nie Xin1; Cai JiaYing1,2; Chen Chen1; Gao Jin1; Miao Hong1; Xu Jie1 |
刊名 | science china-chemistry
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出版日期 | 2010-07-01 |
卷号 | 53期号:7页码:1497-1501 |
关键词 | gold Mg(OH)(2) catalysis oxidation 1 lactic acid 2-propanediol |
英文摘要 | the catalytic oxidation of biomass-derived polyhydroxyl compounds provides an efficient and green route for biomass resource utility. gold nanocrystals supported on mg(oh)(2) were synthesized by sol-immobilization method, characterized by xrd, tem, uv-vis drs, and tested in the selective oxidation of 1,2-propanediol to lactic acid. the gold particle size and the ratio of au to 1,2-propanediol strongly influenced the catalytic activity. over au/mg(oh)(2) with the majority of gold particles concentrated in 14-18 nm, excellent catalytic performance with 94.4% conversion and 89.3% selectivity to lactic acid has been achieved under 0.3 mpa o-2 at 60 degrees c for 6 h. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, multidisciplinary |
研究领域[WOS] | chemistry |
关键词[WOS] | glycerol hydrogenolysis ; propylene-glycol ; on-carbon ; catalyst ; gold ; ethylbenzene ; conversion ; chemicals ; styrene |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000280481500008 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141802] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Ma Hong,Nie Xin,Cai JiaYing,et al. Au/Mg(OH)(2): Highly efficient for selective oxidation of 1,2-propanediol to lactic acid with molecular oxygen[J]. science china-chemistry,2010,53(7):1497-1501. |
APA | Ma Hong.,Nie Xin.,Cai JiaYing.,Chen Chen.,Gao Jin.,...&Xu Jie.(2010).Au/Mg(OH)(2): Highly efficient for selective oxidation of 1,2-propanediol to lactic acid with molecular oxygen.science china-chemistry,53(7),1497-1501. |
MLA | Ma Hong,et al."Au/Mg(OH)(2): Highly efficient for selective oxidation of 1,2-propanediol to lactic acid with molecular oxygen".science china-chemistry 53.7(2010):1497-1501. |
入库方式: OAI收割
来源:大连化学物理研究所
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