Epoxidation of Propylene Catalyzed by Reaction-Controlled Phase Transfer Catalyst with in-Situ H2O2
文献类型：期刊论文
| 作者 | Zhang Hengyun; Lue Ying; Li Jun; Gao Shuang; Xi Zuwei |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2010-10-01 |
| 卷号 | 31期号:10页码:1253-1256 |
| 关键词 | propylene epoxidation propylene oxide heteropolyphosphatotungstate reaction-controlled phase-transfer catalysis hydrogen peroxide |
| 英文摘要 | the epoxidation of propylene catalyzed by a reaction-controlled phase transfer catalyst with h2o2 generated by the oxidation of 2-ethylanthrahydroquinone with molecular oxygen in the organic solvent was investigated. effects of reaction temperature, reaction time, h2o2 concentration, catalyst concentration, and additives on the epoxidation were studied. under the suitable conditions, the yield of propylene oxide, based on 2-ethylanthrahydroquinone, was above 85.6% in the fifth cycle. the results of p-31 mas nmr of the recovered catalyst showed that the catalyst composition tended to being stable after the third cycle. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | oxide |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000284388000011 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141813]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Hengyun,Lue Ying,Li Jun,et al. Epoxidation of Propylene Catalyzed by Reaction-Controlled Phase Transfer Catalyst with in-Situ H2O2[J]. chinese journal of catalysis,2010,31(10):1253-1256. |
| APA | Zhang Hengyun,Lue Ying,Li Jun,Gao Shuang,&Xi Zuwei.(2010).Epoxidation of Propylene Catalyzed by Reaction-Controlled Phase Transfer Catalyst with in-Situ H2O2.chinese journal of catalysis,31(10),1253-1256. |
| MLA | Zhang Hengyun,et al."Epoxidation of Propylene Catalyzed by Reaction-Controlled Phase Transfer Catalyst with in-Situ H2O2".chinese journal of catalysis 31.10(2010):1253-1256. |
入库方式： OAI收割
来源：大连化学物理研究所
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