Chromium-containing carbon film on stainless steel as bipolar plates for proton exchange membrane fuel cells
文献类型：期刊论文
| 作者 | Wu, Bo1; Lin, Guoqiang1; Fu, Yu2; Hou, Ming2; Yi, Baolian2 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2010-12-01 |
| 卷号 | 35期号:24页码:13255-13261 |
| 关键词 | Chromium-containing carbon film Stainless steel bipolar plates Pulsed bias arc ion plating |
| 英文摘要 | a series of chromium-containing carbon films are deposited on 316l stainless steel (ss316l) as bipolar plates for proton exchange membrane fuel cells (pemfcs) by pulsed bias arc ion plating (pbaip). the film characterizations are evaluated by x-ray photoelectron spectroscopy (xps) and x-ray diffractometry (xrd). interfacial contact resistance (icr) between the coated ss316l samples and carbon paper is measured. potentiodynamic and potentiostatic tests in the simulated corrosive circumstance of pemfc are conducted to evaluate the corrosion resistance of the coated ss316l samples. the results indicate the films are primarily composed of pure carbon atoms with amorphous structure, including sp(3) and sp(2) carbon atoms. the contents of sp(3) and sp(2) carbon atom are remarkably influenced by the doping chromium. icr and corrosion resistance of the coated ss316l sample are greatly improved owing to the surface film. the lowest icr between the coated ss316l sample and carbon paper is only 2.8 m omega cm(2) at the compaction force of 120 n cm(-2). the icr has a close relationship with the contents of sp(3) and sp(2) carbon atom, and the lowest icr is obtained for the cr(0.23)c(0.77) film with the lowest sp(3) carbon atom content and highest sp(2) carbon atom content. the ss316l sample with cr(0.23)c(0.77) film also exhibits the best corrosion resistance. finally, the variations of icr and surface morphology of the coated sample before and after corrosion testing are discussed. crown copyright (c) 2010 published by elsevier ltd on behalf of professor t. nejat veziroglu. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | thermal nitridation ; cr-nitrides ; ni-50cr ; alloys ; cost ; xps |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000284967100015 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141815]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Minist Educ, Key Lab Mat Modificat Laser Ion & Elect Beams, Dalian 116085, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Fuel Cell R&D Ctr, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wu, Bo,Lin, Guoqiang,Fu, Yu,et al. Chromium-containing carbon film on stainless steel as bipolar plates for proton exchange membrane fuel cells[J]. international journal of hydrogen energy,2010,35(24):13255-13261. |
| APA | Wu, Bo,Lin, Guoqiang,Fu, Yu,Hou, Ming,&Yi, Baolian.(2010).Chromium-containing carbon film on stainless steel as bipolar plates for proton exchange membrane fuel cells.international journal of hydrogen energy,35(24),13255-13261. |
| MLA | Wu, Bo,et al."Chromium-containing carbon film on stainless steel as bipolar plates for proton exchange membrane fuel cells".international journal of hydrogen energy 35.24(2010):13255-13261. |
入库方式： OAI收割
来源：大连化学物理研究所
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