Development and Application of A Membrane Inlet-Single Photon Ionization-Mass Spectrometer for On- line Analysis Volatile Organic Compounds in Water
文献类型：期刊论文
| 作者 | Cui Hua-Peng1,2; Hou Ke-Yong1; Wu Qing-Hao1,2; Hua Lei1,2; Chen Ping1,2; Ju Bang-Yu1; Li Lin1; Wang Zhen-Xin1; Li Jing-Hua1; Li Hai-Yang1 |
| 刊名 | chinese journal of analytical chemistry
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 38期号:5页码:760-764 |
| 关键词 | Membrane inlet Single photon ionization Time of flight-mass spectrometer Volatile organic compounds On-line analysis |
| 英文摘要 | a single photon ionization time of flight mass spectrometer with membrane inlet has been described and applied for on-line measuring volatile organic compounds (vocs) in water. automatic sampling, enrichment and measurement of vocs were achieved by using a polyolimethyl siloxane (pdms) membrane with a thickness of 50 mu m, a peristaltic pump and electric switch valve. there is almost no memory effect in the membrane inlet system. single photon ionization processes were accomplished with photons of 10.6 ev emitted from a commercial low pressure discharge krypton lamp, and almost no free fragment was found in mass spectrum. thus, it can be used for chemical compounds identification according to their molecular weight. the response times for benzene, toluene, xylene and chlorobenzene were all shorter than 100 s. the detection limit of benzene is 3 x 10(-9) (volume fraction), and an excellent linear response was observed in the range of 10 x 10(-9) (v/v) to 1 x 10(-6) (wv). the instrument was tested to analyze vocs in the sewerage from a chemical plant, and more than twenty compounds of vocs with concentration in 10 x 10(-9) (v/v) level were observed in 200 s. the results indicate that the single photon time-of-flight mass spectrometer with membrane inlet has a great application potential for on-line analyzing vocs in water. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | electrospray-ionization ; ambient conditions ; trace organics ; air |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000278208600031 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141819]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 10039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui Hua-Peng,Hou Ke-Yong,Wu Qing-Hao,et al. Development and Application of A Membrane Inlet-Single Photon Ionization-Mass Spectrometer for On- line Analysis Volatile Organic Compounds in Water[J]. chinese journal of analytical chemistry,2010,38(5):760-764. |
| APA | Cui Hua-Peng.,Hou Ke-Yong.,Wu Qing-Hao.,Hua Lei.,Chen Ping.,...&Li Hai-Yang.(2010).Development and Application of A Membrane Inlet-Single Photon Ionization-Mass Spectrometer for On- line Analysis Volatile Organic Compounds in Water.chinese journal of analytical chemistry,38(5),760-764. |
| MLA | Cui Hua-Peng,et al."Development and Application of A Membrane Inlet-Single Photon Ionization-Mass Spectrometer for On- line Analysis Volatile Organic Compounds in Water".chinese journal of analytical chemistry 38.5(2010):760-764. |
入库方式： OAI收割
来源：大连化学物理研究所
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