中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of TiF3 on the Dehydrogenation of LiAlH4

文献类型:期刊论文

作者Liu Shu-Sheng1,2; Sun Li-Xian1; Song Li-Fang1,2; Jiang Chun-Hong1,2; Zhang Jian1; Zhang Yao1; Xu Fen3; Zhang Zhi-Heng4
刊名chemical journal of chinese universities-chinese
出版日期2010-04-10
卷号31期号:4页码:796-799
关键词TiF3 LiAlH4 Dehydrogenation Catalyze
英文摘要the dehydrogenation performances of as-received, ball-milled and different amounts of tif3 doped lialh4 were investigated by x-ray diffraction(xrd), fourier transformed infrared spectrometer(etir) and thermogravimetry(tg) measurements. it was found that lialh4 decomposes a little during ball milling in the presence of tif3. tif3 has dramatically catalyzed the dehydrogenation of lialh4. with increasing amount of tif,, the initial temperature of dehydrogenation decreases to some extent, hut it sacrifices the dehydrogenation amount at great cost. 2% (molar fraction) tif3-doped lialh4 begins to release h-2 at 80 degrees c, 70 degrees c lower than as-received lialh4, and can release as much as 6.6% (mass fraction) h-2.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, multidisciplinary
研究领域[WOS]chemistry
关键词[WOS]hydrogen storage properties ; alloys
收录类别SCI
语种英语
WOS记录号WOS:000277223700034
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/141828]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
3.Liaoning Normal Univ, Chem & Chem Engn Sch, Dalian 116029, Peoples R China
4.PetroChina Pipeline R&D Ctr, Langfang 065000, Peoples R China
推荐引用方式
GB/T 7714
Liu Shu-Sheng,Sun Li-Xian,Song Li-Fang,et al. Effect of TiF3 on the Dehydrogenation of LiAlH4[J]. chemical journal of chinese universities-chinese,2010,31(4):796-799.
APA Liu Shu-Sheng.,Sun Li-Xian.,Song Li-Fang.,Jiang Chun-Hong.,Zhang Jian.,...&Zhang Zhi-Heng.(2010).Effect of TiF3 on the Dehydrogenation of LiAlH4.chemical journal of chinese universities-chinese,31(4),796-799.
MLA Liu Shu-Sheng,et al."Effect of TiF3 on the Dehydrogenation of LiAlH4".chemical journal of chinese universities-chinese 31.4(2010):796-799.

入库方式: OAI收割

来源:大连化学物理研究所

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