CONVENIENT SYNTHESIS OF OPTICALLY PURE 8-METHOXY-2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE AND 2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE
文献类型：期刊论文
| 作者 | Tang, Jie1; Jiang, Guo-Fang1; Zhou, Yong-Gui2 |
| 刊名 | heterocycles
 |
| 出版日期 | 2010-12-31 |
| 卷号 | 82期号:1页码:887-893 |
| 关键词 | Chemical Resolution Hydrogenation Chiral Tetrahydroquinoline |
| 英文摘要 | a convenient method was developed to synthesize optically pure 8-methoxy-2-methyl-1,2,3,4-tetrahydroquinoline (2a) and 2-methyl-1,2,3,4-tetrahydroquinoline (2b) by combining the methods of catalytic hydrogenation and classical resolution. the catalytic system ([ru(p-cymene)cl(2)](2)/i(2)) showed high efficiency in preparing racemic 2a and 2b, which were successfully resolved using commercial tartaric acid derivatives, and both enantiomers were obtained in moderate yield with >99% ee. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | iridium-catalyzed hydrogenation ; asymmetric hydrogenation ; galipea-officinalis ; heteroaromatic-compounds ; kinetic resolution ; quinolines ; alkaloids ; (+/-)-2-methyl-1,2,3,4-tetrahydroquinoline ; (+/-)-2-methylindoline ; ligands |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000286906100064 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141833]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Jie,Jiang, Guo-Fang,Zhou, Yong-Gui. CONVENIENT SYNTHESIS OF OPTICALLY PURE 8-METHOXY-2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE AND 2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE[J]. heterocycles,2010,82(1):887-893. |
| APA | Tang, Jie,Jiang, Guo-Fang,&Zhou, Yong-Gui.(2010).CONVENIENT SYNTHESIS OF OPTICALLY PURE 8-METHOXY-2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE AND 2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE.heterocycles,82(1),887-893. |
| MLA | Tang, Jie,et al."CONVENIENT SYNTHESIS OF OPTICALLY PURE 8-METHOXY-2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE AND 2-METHYL-1,2,3,4-TETRAHYDROQUINOLINE".heterocycles 82.1(2010):887-893. |
入库方式： OAI收割
来源：大连化学物理研究所
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