Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons
文献类型:期刊论文
作者 | Zhao, Xiaochen1,3; Wang, Aiqin1; Yan, Jingwang2; Sun, Gongquan2; Sun, Lixian; Zhang, Tao1 |
刊名 | chemistry of materials
![]() |
出版日期 | 2010-10-12 |
卷号 | 22期号:19页码:5463-5473 |
英文摘要 | heteroatom-ineorporated 2d ordered mesoporous carbons (omcs) were fabricated via a one-pot organic organic aqueous self-assembly approach, using resorcinol (ft) and formaldehyde (f) as the carbon precursor and triblock copolymer pluronic f127 as the mesoporous structure template. in this approach, rf resin, boric acid and/or phosphoric acid, and f127 underwent a self-assembly process under 4 strong acidic condition to form a polymer with ordered mesostructure, which was then carbonized at 800 degrees c in a nitrogen atmosphere to form b-incorporated, p-incorporated. or 13, p-coincorporated omcs. nitrogen sorption, x-ray diffraction (xrd), and transmission electron microscopy (tem) revealed that the heteroatom-incorporated omcs possessed highly ordered mesoporous structures. uniform pore size distributions, and large surface areas ranging from 500 to 700 m(2)/g. the incorporation of heteroatoms effectively limited the framework shrinkage during the carbonization process, and simultaneously increased the surface oxygen groups in the carbons. the resulting heteroatom-incorporated omcs exhibited superior electrochemical performances to nonincorporated counterpart when used as electrodes or supercapacitors. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
研究领域[WOS] | chemistry ; materials science |
关键词[WOS] | double-layer capacitor ; doped glassy-carbon ; electrodes ; polymers ; boron ; nanocomposites ; connectivity ; degradation ; temperature ; frameworks |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000282471000008 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141834] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Fuel Cell, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Zhao, Xiaochen,Wang, Aiqin,Yan, Jingwang,et al. Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons[J]. chemistry of materials,2010,22(19):5463-5473. |
APA | Zhao, Xiaochen,Wang, Aiqin,Yan, Jingwang,Sun, Gongquan,Sun, Lixian,&Zhang, Tao.(2010).Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons.chemistry of materials,22(19),5463-5473. |
MLA | Zhao, Xiaochen,et al."Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons".chemistry of materials 22.19(2010):5463-5473. |
入库方式: OAI收割
来源:大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。