中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons

文献类型:期刊论文

作者Zhao, Xiaochen1,3; Wang, Aiqin1; Yan, Jingwang2; Sun, Gongquan2; Sun, Lixian; Zhang, Tao1
刊名chemistry of materials
出版日期2010-10-12
卷号22期号:19页码:5463-5473
英文摘要heteroatom-ineorporated 2d ordered mesoporous carbons (omcs) were fabricated via a one-pot organic organic aqueous self-assembly approach, using resorcinol (ft) and formaldehyde (f) as the carbon precursor and triblock copolymer pluronic f127 as the mesoporous structure template. in this approach, rf resin, boric acid and/or phosphoric acid, and f127 underwent a self-assembly process under 4 strong acidic condition to form a polymer with ordered mesostructure, which was then carbonized at 800 degrees c in a nitrogen atmosphere to form b-incorporated, p-incorporated. or 13, p-coincorporated omcs. nitrogen sorption, x-ray diffraction (xrd), and transmission electron microscopy (tem) revealed that the heteroatom-incorporated omcs possessed highly ordered mesoporous structures. uniform pore size distributions, and large surface areas ranging from 500 to 700 m(2)/g. the incorporation of heteroatoms effectively limited the framework shrinkage during the carbonization process, and simultaneously increased the surface oxygen groups in the carbons. the resulting heteroatom-incorporated omcs exhibited superior electrochemical performances to nonincorporated counterpart when used as electrodes or supercapacitors.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, physical ; materials science, multidisciplinary
研究领域[WOS]chemistry ; materials science
关键词[WOS]double-layer capacitor ; doped glassy-carbon ; electrodes ; polymers ; boron ; nanocomposites ; connectivity ; degradation ; temperature ; frameworks
收录类别SCI
语种英语
WOS记录号WOS:000282471000008
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/141834]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Lab Fuel Cell, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Xiaochen,Wang, Aiqin,Yan, Jingwang,et al. Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons[J]. chemistry of materials,2010,22(19):5463-5473.
APA Zhao, Xiaochen,Wang, Aiqin,Yan, Jingwang,Sun, Gongquan,Sun, Lixian,&Zhang, Tao.(2010).Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons.chemistry of materials,22(19),5463-5473.
MLA Zhao, Xiaochen,et al."Synthesis and Electrochemical Performance of Heteroatom-Incorporated Ordered Mesoporous Carbons".chemistry of materials 22.19(2010):5463-5473.

入库方式: OAI收割

来源:大连化学物理研究所

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