Transition-State Spectroscopy of Partial Wave Resonances in the F plus HD Reaction
文献类型:期刊论文
作者 | Dong, Wenrui; Xiao, Chunlei; Wang, Tao; Dai, Dongxu; Yang, Xueming; Zhang, Dong H. |
刊名 | science
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出版日期 | 2010-03-19 |
卷号 | 327期号:5972页码:1501-1502 |
英文摘要 | partial wave resonances, quasi-bound resonance states with well-defined rotation in the transition state region of a chemical reaction, play a governing role in reaction dynamics but have eluded direct experimental characterization. here, we report the observation of individual partial wave resolved resonances in the f + hd -> hf + d reaction by measuring the collision energy-dependent, angle-and state-resolved differential cross section with extremely high resolution, providing a spectroscopic probe to the transition state of f + hd -> hf + d. the agreement of the data with the high-level theoretical calculations confirms the sensitivity of this probe to the subtle quantum mechanical factors guiding this benchmark reaction. |
WOS标题词 | science & technology |
类目[WOS] | multidisciplinary sciences |
研究领域[WOS] | science & technology - other topics |
关键词[WOS] | chemical-reaction |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000275715200045 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141838] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Dong, Wenrui,Xiao, Chunlei,Wang, Tao,et al. Transition-State Spectroscopy of Partial Wave Resonances in the F plus HD Reaction[J]. science,2010,327(5972):1501-1502. |
APA | Dong, Wenrui,Xiao, Chunlei,Wang, Tao,Dai, Dongxu,Yang, Xueming,&Zhang, Dong H..(2010).Transition-State Spectroscopy of Partial Wave Resonances in the F plus HD Reaction.science,327(5972),1501-1502. |
MLA | Dong, Wenrui,et al."Transition-State Spectroscopy of Partial Wave Resonances in the F plus HD Reaction".science 327.5972(2010):1501-1502. |
入库方式: OAI收割
来源:大连化学物理研究所
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