Effect of Pd loading and precursor on the catalytic performance of Pd/WO3-ZrO2 catalysts for selective oxidation of ethylene
文献类型:期刊论文
作者 | Wang, Lixia1,2; Xu, Shuliang1,2; Chu, Wenling1; Yang, Weishen1 |
刊名 | catalysis today
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出版日期 | 2010-01-15 |
卷号 | 149期号:1-2页码:163-166 |
关键词 | Pd/WO3-ZrO2 Pd loading Pd precursors Polytungstates Pd species |
英文摘要 | the structure and properties of pd/wo3-zro2 (w/zr=0.2) catalysts with different pd loadings and precursors were investigated. the results indicate that pd/wo3-zro2 prepared from a pdcl2 precursor was optimum for high activity and selectivity. moreover, ethylene conversion increased with the pd loading the structure and nature of the catalysts were characterized using x-ray diffraction, bet n-2 adsorption, h-2 temperature-programmed reduction and h-2 pulse adsorption techniques the results reveal that the higher catalytic performance of pd/wo3-zro2 prepared from pdcl2 could be related to the formation of polytungstate species and the existence of well-dispersed pd particles. (c) 2009 elsevier b.v all rights reserved |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | acetic-acid ; sol-gel ; palladium ; isomerization ; pd/al2o3 |
收录类别 | SCI ; ISTP |
语种 | 英语 |
WOS记录号 | WOS:000274145600026 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141845] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Lixia,Xu, Shuliang,Chu, Wenling,et al. Effect of Pd loading and precursor on the catalytic performance of Pd/WO3-ZrO2 catalysts for selective oxidation of ethylene[J]. catalysis today,2010,149(1-2):163-166. |
APA | Wang, Lixia,Xu, Shuliang,Chu, Wenling,&Yang, Weishen.(2010).Effect of Pd loading and precursor on the catalytic performance of Pd/WO3-ZrO2 catalysts for selective oxidation of ethylene.catalysis today,149(1-2),163-166. |
MLA | Wang, Lixia,et al."Effect of Pd loading and precursor on the catalytic performance of Pd/WO3-ZrO2 catalysts for selective oxidation of ethylene".catalysis today 149.1-2(2010):163-166. |
入库方式: OAI收割
来源:大连化学物理研究所
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