The Cooperative Templating Effect of Organic Amine in the Ionothermal Synthesis of LTA Type Aluminophosphate Molecular Sieves
文献类型：期刊论文
| 作者 | Pei Renyan1,2; Xu Yunpeng1,2; Wei Ying1,2; Wen Guodong1,2; Li Keda1,2; Wang Lei1; Ma Huaijun1; Tian Zhijian1,3; Lin Liwu3 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2010-08-01 |
| 卷号 | 31期号:8页码:1083-1089 |
| 关键词 | ionothermal synthesis aluminophosphate molecular sieve organic amine co-template LTA type structure |
| 英文摘要 | the lta type alummophosphate molecular sieve (alpo(4)-42) was ionothermally synthesized by introducing organic amine into the 1-butyl-3-methylmudazolium bromide ([bmim]br) ionic liquid the as-synthesized products were characterized and the crystallization kinetics was investigated thermal gravimetric analysis, nuclear magnetic resonance spectroscopy, and infrared spectioscopy demonstrated that the organic amine and the cation of the ionic liquid filled in the channels of the molecular sieve together the introduced amine acted as the synergetic templates in a certain aggregated state according to the result of photoluminescence emission spectroscopy the final products varied with the crystallization time, and the kinetic pathway was influenced by the amine concentration, which decreased with the growth of the crystal product during the crystallization the inorganic materials reassembled around these aggregated templates when they exist in a high concentration to form sod or ha cages, resulting in the crystallization of cubic lta framework |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | temperature ionic liquids ; structure-direction ; zeolite synthesis ; silica zeolite ; mixtures ; fluoride ; solvent ; system ; cit-5 ; alpo4 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000282079400032 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141859]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Pei Renyan,Xu Yunpeng,Wei Ying,et al. The Cooperative Templating Effect of Organic Amine in the Ionothermal Synthesis of LTA Type Aluminophosphate Molecular Sieves[J]. chinese journal of catalysis,2010,31(8):1083-1089. |
| APA | Pei Renyan.,Xu Yunpeng.,Wei Ying.,Wen Guodong.,Li Keda.,...&Lin Liwu.(2010).The Cooperative Templating Effect of Organic Amine in the Ionothermal Synthesis of LTA Type Aluminophosphate Molecular Sieves.chinese journal of catalysis,31(8),1083-1089. |
| MLA | Pei Renyan,et al."The Cooperative Templating Effect of Organic Amine in the Ionothermal Synthesis of LTA Type Aluminophosphate Molecular Sieves".chinese journal of catalysis 31.8(2010):1083-1089. |
入库方式： OAI收割
来源：大连化学物理研究所
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