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Chinese Academy of Sciences Institutional Repositories Grid
Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides

文献类型:期刊论文

作者Chen, Lei1; Yu, Guang-Ao1; Li, Fang1; Zhu, Xiaolei1; Zhang, Bei2; Guo, Rui2; Li, Xiaozhi1; Yang, Qihua2; Jin, Shan1; Liu, Chenchen1
刊名journal of organometallic chemistry
出版日期2010-06-15
卷号695期号:14页码:1768-1775
关键词Amination Cross-coupling Halides Palladium Phosphine
英文摘要2-phenylindenyl phosphine ligand can be changed into anionic phosphine ligand in situ and utilized in the palladium-catalyzed buchwald/hartwig amination reactions in dme, providing good to excellent yields of amination products from aryl chlorides, bromides and iodides. (31)p nmr studies show that the resonance for the anionic phosphine appeared between those of the (2-phenylindenyl)-dicyclohexyl phosphonium salt and (2-phenylindenyl) dicyclohexylphosphine. the calculated results were consistent with the experimental results. (c) 2010 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, inorganic & nuclear ; chemistry, organic
研究领域[WOS]chemistry
关键词[WOS]cross-coupling reactions ; c-n ; suzuki-miyaura ; chlorides ; iodides ; bromides ; heteroaryl ; sonogashira ; precatalysts ; temperature
收录类别SCI ; IC ; CCR
语种英语
WOS记录号WOS:000278918100003
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/141907]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Chen, Lei,Yu, Guang-Ao,Li, Fang,et al. Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides[J]. journal of organometallic chemistry,2010,695(14):1768-1775.
APA Chen, Lei.,Yu, Guang-Ao.,Li, Fang.,Zhu, Xiaolei.,Zhang, Bei.,...&Liu, Sheng-Hua.(2010).Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides.journal of organometallic chemistry,695(14),1768-1775.
MLA Chen, Lei,et al."Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides".journal of organometallic chemistry 695.14(2010):1768-1775.

入库方式: OAI收割

来源:大连化学物理研究所

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