Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides
文献类型:期刊论文
作者 | Chen, Lei1; Yu, Guang-Ao1; Li, Fang1; Zhu, Xiaolei1; Zhang, Bei2; Guo, Rui2; Li, Xiaozhi1; Yang, Qihua2; Jin, Shan1; Liu, Chenchen1 |
刊名 | journal of organometallic chemistry
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出版日期 | 2010-06-15 |
卷号 | 695期号:14页码:1768-1775 |
关键词 | Amination Cross-coupling Halides Palladium Phosphine |
英文摘要 | 2-phenylindenyl phosphine ligand can be changed into anionic phosphine ligand in situ and utilized in the palladium-catalyzed buchwald/hartwig amination reactions in dme, providing good to excellent yields of amination products from aryl chlorides, bromides and iodides. (31)p nmr studies show that the resonance for the anionic phosphine appeared between those of the (2-phenylindenyl)-dicyclohexyl phosphonium salt and (2-phenylindenyl) dicyclohexylphosphine. the calculated results were consistent with the experimental results. (c) 2010 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | cross-coupling reactions ; c-n ; suzuki-miyaura ; chlorides ; iodides ; bromides ; heteroaryl ; sonogashira ; precatalysts ; temperature |
收录类别 | SCI ; IC ; CCR |
语种 | 英语 |
WOS记录号 | WOS:000278918100003 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/141907] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Lei,Yu, Guang-Ao,Li, Fang,et al. Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides[J]. journal of organometallic chemistry,2010,695(14):1768-1775. |
APA | Chen, Lei.,Yu, Guang-Ao.,Li, Fang.,Zhu, Xiaolei.,Zhang, Bei.,...&Liu, Sheng-Hua.(2010).Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides.journal of organometallic chemistry,695(14),1768-1775. |
MLA | Chen, Lei,et al."Preparation of anionic phosphine ligands in situ for the palladium-catalyzed Buchwald/Hartwig amination reactions of aryl halides".journal of organometallic chemistry 695.14(2010):1768-1775. |
入库方式: OAI收割
来源:大连化学物理研究所
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