Transition metal substituted polyoxometalates and their application in the direct hydroxylation of benzene to phenol with hydrogen peroxide
文献类型：期刊论文
| 作者 | Chen, Jiaqi1,2; Li, Jun1; Zhang, Yi1; Gao, Shuang1 |
| 刊名 | research on chemical intermediates
 |
| 出版日期 | 2010-11-01 |
| 卷号 | 36期号:8页码:959-968 |
| 关键词 | Hydroxylation Benzene Phenol Transition metal substituted polyoxometalates |
| 英文摘要 | a series of transition metal substituted polyoxometalates with a keggin structure were prepared and utilized for the hydroxylation of benzene to phenol. among the compounds tested, [(ch3)(4)n](4)pmo11vo40 exhibits the highest phenol yield (13.0%) and selectivity (90.6%) in acetic acid/acetonitrile. vanadium peroxo is the active site of the reaction, and ammonium also plays an important role. the influence of various reaction parameters, such as solvent, reaction time, reaction temperature, and amount of hydrogen peroxide used were investigated to obtain the optimal reaction conditions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | liquid-phase oxidation ; modified titanium silicalite ; heteropolyacid catalysts ; selective hydroxylation ; palladium membrane ; nitrous-oxide ; vanadium ; heteropolymolybdates ; oxygen ; w-183 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000285375600006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141921]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen, Jiaqi,Li, Jun,Zhang, Yi,et al. Transition metal substituted polyoxometalates and their application in the direct hydroxylation of benzene to phenol with hydrogen peroxide[J]. research on chemical intermediates,2010,36(8):959-968. |
| APA | Chen, Jiaqi,Li, Jun,Zhang, Yi,&Gao, Shuang.(2010).Transition metal substituted polyoxometalates and their application in the direct hydroxylation of benzene to phenol with hydrogen peroxide.research on chemical intermediates,36(8),959-968. |
| MLA | Chen, Jiaqi,et al."Transition metal substituted polyoxometalates and their application in the direct hydroxylation of benzene to phenol with hydrogen peroxide".research on chemical intermediates 36.8(2010):959-968. |
入库方式： OAI收割
来源：大连化学物理研究所
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