Low-temperature heat capacities and thermodynamic properties of ethylenediammonium tetrachlorozincate chloride (C2H10N2)(2)(ZnCl4)Cl-2
文献类型：期刊论文
| 作者 | He, Dong-Hua1; Di, You-Ying1; Wang, Bin1; Dan, Wen-Yan1; Tan, Zhi-Cheng2 |
| 刊名 | thermochimica acta
 |
| 出版日期 | 2010-07-10 |
| 卷号 | 506期号:1-2页码:41-46 |
| 关键词 | Ethylenediammonium tetrachlorozincate chloride X-ray crystallography Low-temperature heat capacity Isoperibol solution-reaction calorimetry Standard molar enthalpy of formation |
| 英文摘要 | the ethylenediammonium tetrachlorozincate chloride (c2h10n2)(2)(zncl4)cl-2 was synthesized. chemical analysis, elemental analysis, and x-ray crystallography were applied to characterize the composition and crystal structure of the complex. low-temperature heat capacities of the compound were measured by a precision automatic adiabatic calorimeter over the temperature range from t=77-377 k. a polynomial equation of heat capacities as a function of the reduced temperature was fitted by a least square method. based on the polynomial equation, the smoothed heat capacities and thermodynamic functions of the title compound relative to the standard reference temperature 298.15 k were calculated at intervals of 5k. a thermochemical cycle was designed and the enthalpy change of the solid phase reaction of ethylenediamine dihydrochloride with zinc chloride was determined to be delta h-r(m)degrees = -(17.9 +/- 0.6) kj mol(-1) by an isoperibol solution-reaction calorimeter. finally, the standard molar enthalpy of formation of the title compound was derived to be delta h-f(m)degrees[(c2h10n2)(2)(zncl4)cl-2 center dot s] = -(1514.4 +/- 2.7) kj mol(-1) in accordance with hess law. (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | magnetic-properties ; enthalpy ; crystal |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000280280200007 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141929]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Dong-Hua,Di, You-Ying,Wang, Bin,et al. Low-temperature heat capacities and thermodynamic properties of ethylenediammonium tetrachlorozincate chloride (C2H10N2)(2)(ZnCl4)Cl-2[J]. thermochimica acta,2010,506(1-2):41-46. |
| APA | He, Dong-Hua,Di, You-Ying,Wang, Bin,Dan, Wen-Yan,&Tan, Zhi-Cheng.(2010).Low-temperature heat capacities and thermodynamic properties of ethylenediammonium tetrachlorozincate chloride (C2H10N2)(2)(ZnCl4)Cl-2.thermochimica acta,506(1-2),41-46. |
| MLA | He, Dong-Hua,et al."Low-temperature heat capacities and thermodynamic properties of ethylenediammonium tetrachlorozincate chloride (C2H10N2)(2)(ZnCl4)Cl-2".thermochimica acta 506.1-2(2010):41-46. |
入库方式： OAI收割
来源：大连化学物理研究所
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