Low-temperature heat capacities and thermodynamic properties of Mn-3(HEDTA)(2)center dot 10H(2)O
文献类型：期刊论文
| 作者 | Jiao, Cheng-Li1,3; Song, Li-Fang1,3; Jiang, Chun-Hong1,3; Zhang, Jian1; Si, Xiao-Liang1,3; Qiu, Shu-Jun1,3; Wang, Shuang1,3; Sun, Li-Xian1; Xu, Fen2; Li, Fen1 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2010-12-01 |
| 卷号 | 102期号:3页码:1155-1160 |
| 关键词 | EDTA Manganese Molar heat capacity TG TMDSC |
| 英文摘要 | the low-temperature molar heat capacity of crystalline mn-3(hedta)(2)center dot 10h(2)o was measured by temperature-modulated differential scanning calorimetry (tmdsc) for the first time. the thermodynamic parameters such as entropy and enthalpy relative to 298.15 k were calculated based on the above molar heat capacity data. the compound was characterized by powder xrd, ft-ir spectrum. moreover, the thermal decomposition characteristics of mn-3(hedta)(2)center dot 10h(2)o were investigated by thermogravimetry-mass spectrometer (tg-ms). the experimental result through tg measurement shows that a three-step mass loss process exists. h2o, co2, no, and no2 were observed as products for oxidative degradation of mn-3(hedta)(2)center dot 10h(2)o from the ms curves. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | center-dot 3.5h(2)o ; crystal-structure ; modulated dsc ; complexes ; 8-coordinate ; 7-coordinate ; 9-coordinate ; tetrahydrate |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000284433000044 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141955]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Dalian Univ Technol, Lab Mat Modificat Laser Electron & Ion Beams, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiao, Cheng-Li,Song, Li-Fang,Jiang, Chun-Hong,et al. Low-temperature heat capacities and thermodynamic properties of Mn-3(HEDTA)(2)center dot 10H(2)O[J]. journal of thermal analysis and calorimetry,2010,102(3):1155-1160. |
| APA | Jiao, Cheng-Li.,Song, Li-Fang.,Jiang, Chun-Hong.,Zhang, Jian.,Si, Xiao-Liang.,...&Zhao, Ji-Jun.(2010).Low-temperature heat capacities and thermodynamic properties of Mn-3(HEDTA)(2)center dot 10H(2)O.journal of thermal analysis and calorimetry,102(3),1155-1160. |
| MLA | Jiao, Cheng-Li,et al."Low-temperature heat capacities and thermodynamic properties of Mn-3(HEDTA)(2)center dot 10H(2)O".journal of thermal analysis and calorimetry 102.3(2010):1155-1160. |
入库方式： OAI收割
来源：大连化学物理研究所
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