IrFeOx/SiO2-A highly active catalyst for preferential CO oxidation in H-2
文献类型：期刊论文
| 作者 | Zhang, Wansheng; Huang, Yanqiang; Wang, Junhu; Liu, Kuo; Wang, Xiaodong; Wang, Aiqin; Zhang, Tao |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2010-04-01 |
| 卷号 | 35期号:7页码:3065-3071 |
| 关键词 | Iridium Silica supported IrFe catalyst PROX Non-competitive adsorption |
| 英文摘要 | a novel bifunctional catalyst irfeox/sio2, which was very active and selective for preferential oxidation of co under h-2-rich atmosphere, was developed in this study. xrd, h-2-tpr, and chemisorption were applied to characterize three kinds of irfeox/sio2 catalysts prepared by different impregnation sequences. the results indicated that both feox and jr species were highly dispersed on the sio2 support; the reduction of ir species in the fe-promoted ir/sio2 catalyst became easier than those in the ir/sio2, together with the partial reduction of fe2o3; the saturation uptake of o-2 adsorption was greatly enhanced. in-situ drifts, xps, and mossbauer techniques were further applied to detect the structural information on the selected ir-feox/sio2 catalyst prepared by co-impregnation method. a non-competitive adsorption catalytic mechanism was proposed where co adsorbed on it sites and o-2 adsorbed on feox sites; the reaction probably took place at the interface of ir and feox or via a spill-over process. (c) 2009 professor t. nejat veziroglu. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | carbon-supported catalysts ; fuel-cell applications ; h-2-rich gas streams ; selective oxidation ; metal-catalysts ; monoxide ; fe ; promotion ; prox ; h2o |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000276692800090 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141956]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Wansheng,Huang, Yanqiang,Wang, Junhu,et al. IrFeOx/SiO2-A highly active catalyst for preferential CO oxidation in H-2[J]. international journal of hydrogen energy,2010,35(7):3065-3071. |
| APA | Zhang, Wansheng.,Huang, Yanqiang.,Wang, Junhu.,Liu, Kuo.,Wang, Xiaodong.,...&Zhang, Tao.(2010).IrFeOx/SiO2-A highly active catalyst for preferential CO oxidation in H-2.international journal of hydrogen energy,35(7),3065-3071. |
| MLA | Zhang, Wansheng,et al."IrFeOx/SiO2-A highly active catalyst for preferential CO oxidation in H-2".international journal of hydrogen energy 35.7(2010):3065-3071. |
入库方式： OAI收割
来源：大连化学物理研究所
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