A Fiber-Optic Evanescent Wave O-2 Sensor Based on Ru(II)-Doped Fluorinated ORMOSILs
文献类型：期刊论文
| 作者 | Xiong, Yan; Zhu, Daoqian; Chen, Shiheng; Peng, Hong; Guan, Yafeng |
| 刊名 | journal of fluorescence
 |
| 出版日期 | 2010 |
| 卷号 | 20期号:1页码:269-274 |
| 关键词 | Fiber-optic sensor Evanescent wave Hybrid fluorinated ORMOSILs Oxygen detection |
| 英文摘要 | a novel fiber-optic evanescent wave sensor (foews) for o-2 detection based on [ru(bpy)(3)](2+)-doped hybrid fluorinated ormosils (organically modified silicates) has been developed. the sensing element was fabricated by dip-coating the optical fiber with [ru(bpy)(3)](2+)-doped hybrid fluorinated ormosils composed of n-propyltrimethoxysilane (n-propyl-trimos) and 3, 3, 3-trifluoropropyltrimethoxysilane (tfp-trimos). fluorophores of [ru(bpy)(3)](2+) were excited by the evanescent wave field produced on the fiber core surface and the emission fluorescence was quenched by o-2. spectroscopic properties have been characterized by ftir and uv-vis absorption measurements. by using the presented hybrid fluorinated ormosils, which enhances the coating surface hydrophobicity, the quenching response is increased. the sensitivity of the sensor is 7.5, which is quantified in terms of the ratio i (n2)/i (o2) (i (n2) and i (o2) represent the fluorescence intensities in pure n-2 and pure o-2 environments, respectively). the limit of detection (l.o.d.) is 0.01% (3 sigma) and the response time is about 1 s. meanwhile, the proposed foews has the advantages of easy fabrication, low cost, fast response and suitable sensitivity for oxygen monitoring using a cheap blue led as light source and coupling a miniature pmt detector directly to the optical fiber probe. |
| WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
| 类目[WOS] | biochemical research methods ; chemistry, analytical |
| 研究领域[WOS] | biochemistry & molecular biology ; chemistry |
| 关键词[WOS] | optical oxygen sensor ; sol-gel materials ; dissolved-oxygen ; spectroscopy ; nanosensors ; sensitivity ; calibration ; complexes ; system ; cells |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000274401600031 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141973]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dept Instrumentat & Analyt Chem, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiong, Yan,Zhu, Daoqian,Chen, Shiheng,et al. A Fiber-Optic Evanescent Wave O-2 Sensor Based on Ru(II)-Doped Fluorinated ORMOSILs[J]. journal of fluorescence,2010,20(1):269-274. |
| APA | Xiong, Yan,Zhu, Daoqian,Chen, Shiheng,Peng, Hong,&Guan, Yafeng.(2010).A Fiber-Optic Evanescent Wave O-2 Sensor Based on Ru(II)-Doped Fluorinated ORMOSILs.journal of fluorescence,20(1),269-274. |
| MLA | Xiong, Yan,et al."A Fiber-Optic Evanescent Wave O-2 Sensor Based on Ru(II)-Doped Fluorinated ORMOSILs".journal of fluorescence 20.1(2010):269-274. |
入库方式： OAI收割
来源：大连化学物理研究所
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