Effects of Calcium and Vanadium Ions on the Epoxidation of Cyclohexene with H2O2 Catalyzed by Vanadium Bromoperoxidase
文献类型：期刊论文
| 作者 | Zhang Biaoming1,2; Cao Xupeng1; Xue Song1; Xiao Tonghu3; Zhang Wei1,4 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2010-10-01 |
| 卷号 | 31期号:10页码:1293-1299 |
| 关键词 | bromoperoxidase calcium ion vanadium ion cyclohexene hydrogen peroxide epoxidation epoxycyclohexane |
| 英文摘要 | vanadium bromoperoxidase (v-bpo) from a marine macro-alga corallina officinalis can catalyze the epoxidation of cyclohexene in the presence of kbr to form epoxycyclohexane using h2o2 as the oxidant. a process intensification strategy has been developed by the integration of v-bpo pretreatment, continuous feeding of h2o2, and optimizing reaction conditions in order to improve the epoxidation productivity. the bpo activity and thermostability increased significantly when the v-bpo solution was dialyzed with a buffer containing 1.0 mmol/l vanadium ion and 1.0 mmol/l calcium ion. the apparent enzyme activity was improved when the h2o2 was fed continuously using a constant flow pump. when combined with the optimal reaction conditions (including buffer, ph, temperature, enzyme concentration, and kbr and h2o2 concentrations), the space-time yield of epoxycyclohexane and its yield to hydrogen peroxide reached 4.79 g/(l.h) and 74%, respectively. these values are 78% increasing than the highest values reported previously. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | corallina-pilulifera ; organic-synthesis ; haloperoxidases ; chloroperoxidase ; oxidation ; bromination ; peroxidases ; stability |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000284388000018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/141976]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Ningbo Univ, Fac Mat Sci & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China 4.Flinders Univ S Australia, Flinders Ctr Marine Bioproc & Bioprod, Adelaide, SA 5042, Australia |
| 推荐引用方式 GB/T 7714 | Zhang Biaoming,Cao Xupeng,Xue Song,et al. Effects of Calcium and Vanadium Ions on the Epoxidation of Cyclohexene with H2O2 Catalyzed by Vanadium Bromoperoxidase[J]. chinese journal of catalysis,2010,31(10):1293-1299. |
| APA | Zhang Biaoming,Cao Xupeng,Xue Song,Xiao Tonghu,&Zhang Wei.(2010).Effects of Calcium and Vanadium Ions on the Epoxidation of Cyclohexene with H2O2 Catalyzed by Vanadium Bromoperoxidase.chinese journal of catalysis,31(10),1293-1299. |
| MLA | Zhang Biaoming,et al."Effects of Calcium and Vanadium Ions on the Epoxidation of Cyclohexene with H2O2 Catalyzed by Vanadium Bromoperoxidase".chinese journal of catalysis 31.10(2010):1293-1299. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。