A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins
文献类型：期刊论文
| 作者 | Gao, Ying-Xiang2,3; Chang, Le2,3; Shi, Hang2,3; Liang, Bo2,3; Wongkhan, Kittiya1; Chaiyaveij, Duangduan1; Batsanov, Andrei S.1; Marder, Todd B.1; Li, Chuang-Chuang2,3; Yang, Zhen2,3 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2010-08-01 |
| 卷号 | 352期号:11-12页码:1955-1966 |
| 关键词 | asymmetric catalysis catalyst design enantioselectivity palladium thiourea-oxazoline library |
| 英文摘要 | we report herein the synthesis of novel chiral s,n-heterobidentate thiourea-oxazoline ligands and their application to palladium-catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. copper salts were found to play multiple roles in this reaction. substituted 2-phenylsuccinates were obtained in >90% yield and up to 84% cc under optimized conditions. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | pauson-khand reaction ; asymmetric bis(alkoxycarbonylation) reaction ; hydride transfer reduction ; cross-coupling reactions ; bis-alkoxycarbonylation ; carbon-monoxide ; silver-nitrate ; carbonylative annulation ; supported catalysts ; bioxazoline ligand |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000281654500024 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142000]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Durham, Dept Chem, Durham DH1 3LE, England 2.Peking Univ, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China 3.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, BNLMS,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gao, Ying-Xiang,Chang, Le,Shi, Hang,et al. A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins[J]. advanced synthesis & catalysis,2010,352(11-12):1955-1966. |
| APA | Gao, Ying-Xiang.,Chang, Le.,Shi, Hang.,Liang, Bo.,Wongkhan, Kittiya.,...&Huang, Yong.(2010).A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins.advanced synthesis & catalysis,352(11-12),1955-1966. |
| MLA | Gao, Ying-Xiang,et al."A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins".advanced synthesis & catalysis 352.11-12(2010):1955-1966. |
入库方式： OAI收割
来源：大连化学物理研究所
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