Readily available chiral phosphine-aminophosphine ligands derived from 1-phenylethylamine for Rh-catalyzed enantioselective hydrogenations
文献类型：期刊论文
| 作者 | Zhou, Xiao-Mao2; Huang, Jia-Di1; Luo, Li-Bin2; Zhang, Cheng-Lu3; Zheng, Zhuo1; Hu, Xiang-Ping1 |
| 刊名 | tetrahedron-asymmetry
 |
| 出版日期 | 2010-03-16 |
| 卷号 | 21期号:4页码:420-424 |
| 英文摘要 | a series of new chiral phosphine-aminophosphine ligands have been prepared via a two- or three-step transformation from commercially available and inexpensive (s)-1-phenylethylamine, and successfully used in the rhodium-catalyzed asymmetric hydrogenation of various enamides, beta-dehydroamino acid esters, and dimethyl itaconate. the results show that the ligand structure plays an important influence on both the reactivity and enantioselectivity. ligand 2d bearing a n-h proton and two f-atoms on the 3,5-positions of the phenyl ring of the aminophosphino moiety was most effective for the hydrogenation of enamides and (z)-beta-aryl-beta-(acylamino)acrylates, whereas ligand lb showed the highest enantioselectivities in the hydrogenation of (z)-beta-alkyl-beta-(acylamino)acrylates and dimethyl itaconate. (c) 2010 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | amino acid-derivatives ; n-h proton ; asymmetric hydrogenation ; phosphoramidite ligands ; practical ligands ; roche ester ; indolphos ; quinaphos ; aryl ; beta-(acylamino)acrylates |
| 收录类别 | SCI ; IC |
| 语种 | 英语 |
| WOS记录号 | WOS:000277825700008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142030]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Hunan Agr Univ, Inst Pesticide, Changsha 410128, Hunan, Peoples R China 3.Liaoning Normal Univ, Sch Chem & Chem Engn, Dalian 116029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Xiao-Mao,Huang, Jia-Di,Luo, Li-Bin,et al. Readily available chiral phosphine-aminophosphine ligands derived from 1-phenylethylamine for Rh-catalyzed enantioselective hydrogenations[J]. tetrahedron-asymmetry,2010,21(4):420-424. |
| APA | Zhou, Xiao-Mao,Huang, Jia-Di,Luo, Li-Bin,Zhang, Cheng-Lu,Zheng, Zhuo,&Hu, Xiang-Ping.(2010).Readily available chiral phosphine-aminophosphine ligands derived from 1-phenylethylamine for Rh-catalyzed enantioselective hydrogenations.tetrahedron-asymmetry,21(4),420-424. |
| MLA | Zhou, Xiao-Mao,et al."Readily available chiral phosphine-aminophosphine ligands derived from 1-phenylethylamine for Rh-catalyzed enantioselective hydrogenations".tetrahedron-asymmetry 21.4(2010):420-424. |
入库方式： OAI收割
来源：大连化学物理研究所
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