Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs
文献类型：期刊论文
| 作者 | Song, Li-Fang1,2; Jiang, Chun-Hong1,2; Zhang, Jian1; Sun, Li-Xian1; Xu, Fen3; You, Wan-Sheng3; Zhao, Yi3; Zhang, Zhi-Heng4; Wang, Mei-Han5; Sawada, Yutake5 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 100期号:2页码:679-684 |
| 关键词 | Copper Metal-organic frameworks Molar heat capacity Temperature modulated differential scanning calorimetry Thermogravimetry |
| 英文摘要 | a novel metal-organic frameworks [cu-2(oh)(2,2'-bpy)(2)(btc) center dot a 2h(2)o](n) (cumof, btc = benzene-1,3,5-tricarboxylic acid, 2,2'-bpy = 2,2'-bipyridine) has been synthesized hydrothermally and characterized by single crystal xrd, ft-ir spectra. the low-temperature molar heat capacities were measured by temperature modulated differential scanning calorimetry (tmdsc) for the first time. the thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 k were derived based on the above molar heat capacity data. moreover, the thermal stability and the decomposition mechanism of cumof were investigated by tg-ms (thermogravimetry-mass spectrometer). a four-stage mass loss was observed in the tg curve. ms curve indicated that the gas products for oxidative degradation of cumof were h2o, co2, no and no2. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic frameworks ; modulated dsc |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000276771600040 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142033]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 4.PetroChina Pipeline Co, Inst Appl Chem, R&D Ctr, Langfang 065000, Hebei, Peoples R China 5.Tokyo Polytech Univ, Fac Engn, Dept Nanochem, Kanagawa 2430297, Japan 6.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410076, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Li-Fang,Jiang, Chun-Hong,Zhang, Jian,et al. Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs[J]. journal of thermal analysis and calorimetry,2010,100(2):679-684. |
| APA | Song, Li-Fang.,Jiang, Chun-Hong.,Zhang, Jian.,Sun, Li-Xian.,Xu, Fen.,...&Zeng, Ju-Lan.(2010).Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs.journal of thermal analysis and calorimetry,100(2),679-684. |
| MLA | Song, Li-Fang,et al."Heat capacities and thermodynamic properties of a novel mixed-ligands MOFs".journal of thermal analysis and calorimetry 100.2(2010):679-684. |
入库方式： OAI收割
来源：大连化学物理研究所
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