Gas separation performance of C/CMS membranes derived from poly (furfuryl alcohol) (PFA) with different chemical structure
文献类型：期刊论文
| 作者 | Song, Chengwen1,2; Wang, Tonghua1; Jiang, Huawei1; Wang, Xiuyue1; Cao, Yiming3; Qiu, Jieshan1 |
| 刊名 | journal of membrane science
 |
| 出版日期 | 2010-09-30 |
| 卷号 | 361期号:1-2页码:22-27 |
| 关键词 | Chemical structure Carbon membranes Gas separation Poly(furfuryl alcohol) |
| 英文摘要 | carbon molecular sieve (cms) membranes derived from two kinds of pfas synthesized by oxalic acid and iodine catalyst were prepared respectively. in order to investigate the effect of chemical structure of the pfas on properties of their cms membranes, tg, ftir, xrd and hrtem were employed to characterize the microstructural change of cms membranes during pyrolysis. gas separation performance of cms membranes was also investigated by molecular probe study with pure gases (h(2), co(2), o(2), n(2) and ch(4)). the results show two kinds of pfas are composed of a large amount of same function groups by different cross-linking style, which was confirmed by their similar mr spectra and slightly different tg curves. after pyrolysis, there are significant differences in microstructure and gas permeation for resultant cms membranes. the pfa-oa carbon membrane exhibits high carbon yield, smaller d(0) (02) value (interlayer spacing) and short, slightly irregular but roughly parallel fringes in hrtem. in contrast, the pfa-i carbon membrane shows a higher gas permeability and lower gas permselectivity in gas permeation experiments. (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 类目[WOS] | engineering, chemical ; polymer science |
| 研究领域[WOS] | engineering ; polymer science |
| 关键词[WOS] | carbon molecular-sieve ; nanoporous carbon ; carbonization atmosphere ; polymerization ; resin ; permeation ; composite ; temperature ; pyrolysis ; polyimide |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000280974600003 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142056]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, State key Lab Fine Chem, Carbon Res Lab, Sch Chem Engn, Dalian 116012, Peoples R China 2.Dalian Maritime Univ, Environm Informat Inst, Sch Environm Sci & Engn, Dalian 116026, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song, Chengwen,Wang, Tonghua,Jiang, Huawei,et al. Gas separation performance of C/CMS membranes derived from poly (furfuryl alcohol) (PFA) with different chemical structure[J]. journal of membrane science,2010,361(1-2):22-27. |
| APA | Song, Chengwen,Wang, Tonghua,Jiang, Huawei,Wang, Xiuyue,Cao, Yiming,&Qiu, Jieshan.(2010).Gas separation performance of C/CMS membranes derived from poly (furfuryl alcohol) (PFA) with different chemical structure.journal of membrane science,361(1-2),22-27. |
| MLA | Song, Chengwen,et al."Gas separation performance of C/CMS membranes derived from poly (furfuryl alcohol) (PFA) with different chemical structure".journal of membrane science 361.1-2(2010):22-27. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。