A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis
文献类型:期刊论文
| 作者 | Yu, Weiqiang1,2; Xu, Jie1; Ma, Hong1; Chen, Chen1; Zhao, Jing1,2; Miao, Hong1; Song, Qi1,2 |
| 刊名 | catalysis communications
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| 出版日期 | 2010-01-25 |
| 卷号 | 11期号:5页码:493-497 |
| 关键词 | Carbothermal reduction Glycerol hydrogenolysis Potassium borohydride Propylene glycol |
| 英文摘要 | it reported a novel procedure for preparing ni/ac catalyst for the glycerol hydrogenolysis, which involved carbothermal reduction of supported nickel nitrate and further treatment with kbh4. the activity of the as-prepared catalyst was remarkably enhanced compared with kbh4, h-2 or carbothermal reduced ni/ac catalyst. the ni particles and the variation of oxygen-containing surface groups (osgs) were studied by xrd, tem, ft-ir, he-tpd and nh3-tpd techniques. the high dispersed ni and the acidity generated by the osgs have the synergy effect on the activity of glycerol hydrogenolysis. (c) 2009 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | supported nickel-catalysts ; ion-exchange-resin ; propylene-glycol ; activated carbon ; selective hydrogenolysis ; platinum catalysts ; ni catalysts ; hydrogenation ; ru |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000274273300040 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142089] ![]() |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Weiqiang,Xu, Jie,Ma, Hong,et al. A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis[J]. catalysis communications,2010,11(5):493-497. |
| APA | Yu, Weiqiang.,Xu, Jie.,Ma, Hong.,Chen, Chen.,Zhao, Jing.,...&Song, Qi.(2010).A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis.catalysis communications,11(5),493-497. |
| MLA | Yu, Weiqiang,et al."A remarkable enhancement of catalytic activity for KBH4 treating the carbothermal reduced Ni/AC catalyst in glycerol hydrogenolysis".catalysis communications 11.5(2010):493-497. |
入库方式: OAI收割
来源:大连化学物理研究所
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