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Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1

文献类型:期刊论文

作者Wei, Ying1,2; Gies, Hermann3; Tian, Zhijian1; Marler, Bernd3; Xu, Yunpeng1; Wang, Lei1; Ma, Huaijun1; Pei, Renyan1,2; Li, Keda1,2; Wang, Bingchun1
刊名inorganic chemistry communications
出版日期2010-11-01
卷号13期号:11页码:1357-1360
关键词Ionothermal synthesis Ionic liquids Nickel diphosphate Open-framework Layered structure
英文摘要a new layered ammonium nickel(ii) diphosphate, (nh(4))(2)[ni(3)(p(2)o(7))(2)(h(2)o)(2)], has been synthesized ionothermally in the ionic liquid 1-butyl-3-methyl imidazolium bromide and characterized by powder x-ray diffraction, elemental analysis, scaning electron microscopy, thermogravimetry etc. the results of the characterization show that the crystal adopts the monoclinic space group p2(1)/a with the lattice constants a=9.23529(2) angstrom, b=7.98489(2) angstrom. c=9.40772(2) angstrom, beta=100.2608(2)degrees and z=2. its structure consists of chains of cis- and trans-edge-sharing [nio(6)](-)octahedra linked via [p(2)o(7)] units to form layers of [ni(3)(p(2)o(7))(2) (h(2)o)(2)](2-) in the ab plane. adjacent layers are separated in the c-direction by ammonium ions. (c) 2010 elsevier b.v. all rights reserved.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, inorganic & nuclear
研究领域[WOS]chemistry
关键词[WOS]magnetic-properties ; spectroscopic properties ; hydrothermal synthesis ; phosphate vsb-5 ; aluminophosphate ; behavior ; frameworks ; catalyst
收录类别SCI
语种英语
WOS记录号WOS:000282867800034
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/142090]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
3.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
推荐引用方式
GB/T 7714
Wei, Ying,Gies, Hermann,Tian, Zhijian,et al. Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1[J]. inorganic chemistry communications,2010,13(11):1357-1360.
APA Wei, Ying.,Gies, Hermann.,Tian, Zhijian.,Marler, Bernd.,Xu, Yunpeng.,...&Wang, Bingchun.(2010).Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1.inorganic chemistry communications,13(11),1357-1360.
MLA Wei, Ying,et al."Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1".inorganic chemistry communications 13.11(2010):1357-1360.

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来源:大连化学物理研究所

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