Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1
文献类型:期刊论文
作者 | Wei, Ying1,2; Gies, Hermann3; Tian, Zhijian1; Marler, Bernd3; Xu, Yunpeng1; Wang, Lei1; Ma, Huaijun1; Pei, Renyan1,2; Li, Keda1,2; Wang, Bingchun1 |
刊名 | inorganic chemistry communications
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出版日期 | 2010-11-01 |
卷号 | 13期号:11页码:1357-1360 |
关键词 | Ionothermal synthesis Ionic liquids Nickel diphosphate Open-framework Layered structure |
英文摘要 | a new layered ammonium nickel(ii) diphosphate, (nh(4))(2)[ni(3)(p(2)o(7))(2)(h(2)o)(2)], has been synthesized ionothermally in the ionic liquid 1-butyl-3-methyl imidazolium bromide and characterized by powder x-ray diffraction, elemental analysis, scaning electron microscopy, thermogravimetry etc. the results of the characterization show that the crystal adopts the monoclinic space group p2(1)/a with the lattice constants a=9.23529(2) angstrom, b=7.98489(2) angstrom. c=9.40772(2) angstrom, beta=100.2608(2)degrees and z=2. its structure consists of chains of cis- and trans-edge-sharing [nio(6)](-)octahedra linked via [p(2)o(7)] units to form layers of [ni(3)(p(2)o(7))(2) (h(2)o)(2)](2-) in the ab plane. adjacent layers are separated in the c-direction by ammonium ions. (c) 2010 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, inorganic & nuclear |
研究领域[WOS] | chemistry |
关键词[WOS] | magnetic-properties ; spectroscopic properties ; hydrothermal synthesis ; phosphate vsb-5 ; aluminophosphate ; behavior ; frameworks ; catalyst |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000282867800034 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/142090] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany |
推荐引用方式 GB/T 7714 | Wei, Ying,Gies, Hermann,Tian, Zhijian,et al. Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1[J]. inorganic chemistry communications,2010,13(11):1357-1360. |
APA | Wei, Ying.,Gies, Hermann.,Tian, Zhijian.,Marler, Bernd.,Xu, Yunpeng.,...&Wang, Bingchun.(2010).Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1.inorganic chemistry communications,13(11),1357-1360. |
MLA | Wei, Ying,et al."Ionothermal synthesis and crystal structure of a new layered nickel(II) diphosphate, DRM-1".inorganic chemistry communications 13.11(2010):1357-1360. |
入库方式: OAI收割
来源:大连化学物理研究所
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