Crossed-beam universal-detection reactive scattering of radical beams characterized by laser-induced-fluorescence: the case of C-2 and CN
文献类型：期刊论文
| 作者 | Leonori, Francesca1; Hickson, Kevin M.2; Le Picard, Sebastien D.3; Wang, Xingan4; Petrucci, Raffaele1; Foggi, Paolo1; Balucani, Nadia1; Casavecchia, Piergiorgio1 |
| 刊名 | molecular physics
 |
| 出版日期 | 2010 |
| 卷号 | 108期号:7-9页码:1097-1113 |
| 关键词 | reaction dynamics laser induced fluorescence crossed molecular beam technique radical beams C-2 and CN radicals reactions of CN with unsaturated hydrocarbons |
| 英文摘要 | continuous supersonic beams of dicarbon (c-2) and cyano (cn) radicals have been generated by a high-pressure radio-frequency discharge beam source starting from dilute mixtures in rare gases of suitable precursor molecules. their internal quantum state distributions have been characterized by laser-induced-fluorescence (lif) in a new crossed molecular beam-laser apparatus. these supersonic beams have been used to study the reactive scattering of c-2 and cn radicals with unsaturated hydrocarbons. this paper reports here on the c-2 and cn radical beam characterization by lif and on dynamics studies of the reactions cn+c2h2 (acetylene) and cn+ch3cch (methylacetylene) by the crossed molecular beam scattering technique with universal mass spectrometric detection and time-of-flight analysis. the role of cn rovibrational excitation on the dynamics of the cn+c2h2 reaction is discussed with reference to previous dynamics and kinetics studies. these reactions are of interest in the chemistry of planetary atmospheres (titan) and the interstellar medium as well as in combustion. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | classical trajectory calculations ; fourier-transform spectroscopy ; soft electron-ionization ; molecular-beam ; chemical-dynamics ; cyano radicals ; ab-initio ; hydrocarbon molecules ; elementary reactions ; atomic oxygen |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000278110600026 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142114]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy 2.Univ Bordeaux, CNRS, UMR 5255, Inst Mol Sci, F-33405 Talence, France 3.Univ Rennes 1, CNRS, UMR 6251, Inst Phys Rennes, F-35042 Rennes, France 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Leonori, Francesca,Hickson, Kevin M.,Le Picard, Sebastien D.,et al. Crossed-beam universal-detection reactive scattering of radical beams characterized by laser-induced-fluorescence: the case of C-2 and CN[J]. molecular physics,2010,108(7-9):1097-1113. |
| APA | Leonori, Francesca.,Hickson, Kevin M..,Le Picard, Sebastien D..,Wang, Xingan.,Petrucci, Raffaele.,...&Casavecchia, Piergiorgio.(2010).Crossed-beam universal-detection reactive scattering of radical beams characterized by laser-induced-fluorescence: the case of C-2 and CN.molecular physics,108(7-9),1097-1113. |
| MLA | Leonori, Francesca,et al."Crossed-beam universal-detection reactive scattering of radical beams characterized by laser-induced-fluorescence: the case of C-2 and CN".molecular physics 108.7-9(2010):1097-1113. |
入库方式： OAI收割
来源：大连化学物理研究所
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