Effect of Li Promoter on Catalytic Performance of Rh-Mn/SiO2 for CO Hydrogenation to C-2-Oxygenates
文献类型：期刊论文
| 作者 | Li Jingwei1,3; Ding Yunjie1,2; Lin Ronghe1,3; Gong Leifeng1,3; Song Xiangen1,3; Chen Weimiao1; Wang Tao1; Luo Hongyuan1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2010-03-01 |
| 卷号 | 31期号:3页码:365-369 |
| 关键词 | lithium rhodium manganese silica carbon monoxide hydrogenation C-2-oxygenate |
| 英文摘要 | the influence of li loading on the catalytic activity of li-promoted rh-mn/sio2 catalyst for the synthesis of c-2-oxygenates through co hydrogenation was investigated. the catalyst samples were characterized by volumetric chemisorption, temperature-programmed reduction, temperature-programmed desorption of co, and temperature-programmed surface reaction. the addition of li significantly suppressed the formation of ch4 on the rh-based catalyst, while the selectivity for higher hydrocarbons was little affected. the li promoter largely enhanced the selectivity for c-2-oxygenates, especially that of acetic acid. however, the activity of the rh-based catalyst for co hydrogenation gradually decreased with the increase in li loading. it was suggested that the role of li was to decrease the co dissociation ability and to reduce the number of active sites for co dissociation. the uptakes of h-2 and co on the li-promoted rh-based catalyst were almost the same as those on the rh-mn/sio2 catalyst, which implied that most of li was positioned on the support, and only a small part of the added li was positioned on the top of rh particles. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | carbon-monoxide hydrogenation ; supported rhodium catalysts ; rh-mn-li/sio2 catalyst ; conversion ; lanthana ; rh/sio2 ; rh/tio2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000276535300021 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142145]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Jingwei,Ding Yunjie,Lin Ronghe,et al. Effect of Li Promoter on Catalytic Performance of Rh-Mn/SiO2 for CO Hydrogenation to C-2-Oxygenates[J]. chinese journal of catalysis,2010,31(3):365-369. |
| APA | Li Jingwei.,Ding Yunjie.,Lin Ronghe.,Gong Leifeng.,Song Xiangen.,...&Luo Hongyuan.(2010).Effect of Li Promoter on Catalytic Performance of Rh-Mn/SiO2 for CO Hydrogenation to C-2-Oxygenates.chinese journal of catalysis,31(3),365-369. |
| MLA | Li Jingwei,et al."Effect of Li Promoter on Catalytic Performance of Rh-Mn/SiO2 for CO Hydrogenation to C-2-Oxygenates".chinese journal of catalysis 31.3(2010):365-369. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。