Synthesis and Structure Description of a New Tetradecaborate [H3N(CH2)(2)NH3](2)[B14O20(OH)(6)]
文献类型：期刊论文
| 作者 | Yang Miao1,2; Zhang Zheng1; Ding Hong1; Li Ji-yang1 |
| 刊名 | chemical research in chinese universities
 |
| 出版日期 | 2010-05-25 |
| 卷号 | 26期号:3页码:335-338 |
| 关键词 | Polyborate anion Crystal structure Boric acid "flux" method |
| 英文摘要 | a new tetradecaborate, [h3n(ch2)(2)nh3](2)[b14o20(oh)(6)] , was synthesized by a boric acid 'flux' method, and characterized by x-ray powder diffraction, icp, ir, tga and dta analyses. single-crystal x-ray diffraction analysis showed that it crystallized in the monoclinic space group p (1) over bar (no.2) with a=0.85092(10) nm, b=0.88678(11) nm, c=1.00724(13) nm, alpha=95.099(2), beta=96.950(2), gamma=6.845(2), v=0.66425(14) nm(3), z=2, r-1=0.0625[i>2 sigma(i)], and wr(2)=0.1172(all data). the molecule structure of compound 1 comprises the isolated polyanion clusters [b14o20(oh)(6)](4-) and diprotonated ethylenediamine molecules. each polyanion cluster contains an 8-ring enclosed by six b3o3 3-ring units. adjacent clusters are further connected with each, other through strong hydrogen-bonding interactions of n(o)-h center dot center dot center dot o to form a three dimensional(3d) supramolecular structure with 2d pseudo channels along the [010] and [001] directions. the diprotonated ethylenediamine molecules located in the channels interact with the host through extensive hydrogen-bonds. compound 1 presents few example containing isolated polyborate anions synthesized by a boric acid 'flux' method. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | polyborate anions ; crystal-structure ; 1st examples ; borate ; heptaborate ; chemistry ; oxoanion |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000279304600001 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142158]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yang Miao,Zhang Zheng,Ding Hong,et al. Synthesis and Structure Description of a New Tetradecaborate [H3N(CH2)(2)NH3](2)[B14O20(OH)(6)][J]. chemical research in chinese universities,2010,26(3):335-338. |
| APA | Yang Miao,Zhang Zheng,Ding Hong,&Li Ji-yang.(2010).Synthesis and Structure Description of a New Tetradecaborate [H3N(CH2)(2)NH3](2)[B14O20(OH)(6)].chemical research in chinese universities,26(3),335-338. |
| MLA | Yang Miao,et al."Synthesis and Structure Description of a New Tetradecaborate [H3N(CH2)(2)NH3](2)[B14O20(OH)(6)]".chemical research in chinese universities 26.3(2010):335-338. |
入库方式： OAI收割
来源：大连化学物理研究所
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