Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite
文献类型：期刊论文
| 作者 | Sheng Xuebin1,2; Ma Hong1; Li Decai1; He Jing3; Xu Jie1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2010-07-01 |
| 卷号 | 31期号:7页码:822-826 |
| 关键词 | isoamyl nitrite nitrosonium cation solid sulfonic acid benzyl alcohol oxidation molecular oxygen benzyl aldehyde |
| 英文摘要 | isoamyl nitrite was employed to catalyze the selective oxidation of benzyl alcohol to benzyl aldehyde using molecular oxygen, in which solid sulfonic acid was used to promote the in situ generation of nitrosonium cation. solid acid prepared by treating amberlyst 15 at 300 degrees c demonstrated the best promotion effect, with which 90% conversion and 97% selectivity for benzyl aldehyde could be achieved at 80 degrees c under 0.5 mpa for 2 h. the differences of solid acids and their influence on oxidation were investigated by fourier transform infrared spectroscopy, derivative thermogravimetry, and acid-base titration. nitrosonium cation was detected by the derivative method using ultraviolet-visible absorption spectrometry. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | nonlinear-optical applications ; transition-metal-free ; mild conditions ; heterogeneous system ; sulfuric acid/nano2 ; carbonyl-compounds ; aerobic oxidation ; solvent-free ; oxygen ; dye |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000280868900018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142171]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.PetroChina Urumuqi Petrochem Co Fibre Mill, Urumqi 830019, Xinjiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sheng Xuebin,Ma Hong,Li Decai,et al. Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite[J]. chinese journal of catalysis,2010,31(7):822-826. |
| APA | Sheng Xuebin,Ma Hong,Li Decai,He Jing,&Xu Jie.(2010).Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite.chinese journal of catalysis,31(7),822-826. |
| MLA | Sheng Xuebin,et al."Solid Sulfonic Acid-Promoted Oxidation of Benzyl Alcohol Catalyzed by Isoamyl Nitrite".chinese journal of catalysis 31.7(2010):822-826. |
入库方式： OAI收割
来源：大连化学物理研究所
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