Product rotational Franck-Condon oscillations in HOD (Jka,kc) dissociation
文献类型：期刊论文
| 作者 | Cheng, Lina2; Yuan, Kaijun2; Cheng, Yuan2; Guo, Qing2; Yang, Xueming2; Dixon, Richard N.1 |
| 刊名 | molecular physics
 |
| 出版日期 | 2010 |
| 卷号 | 108期号:7-9页码:905-914 |
| 关键词 | photodissociation HOD Franck-Condon Oscillations |
| 英文摘要 | the technique of h(d) atom photofragment translation spectroscopy has been used to investigate the dissociation of jet-cooled hod molecules following excitation to individual rovibrational levels of its (c) over tilde((1)b(1)) rydberg state near 124 nm. spectra have been recorded for both the d + oh and h + od dissociation channels. the branching ratios between oh/od(x (2)pi, high nu, low n), oh/od(x (2)pi, low nu, high n), and oh/od(a (2)sigma(+)) channels vary between different parent rotational levels, and between the oh and od products. the variation between the oh and od channels can be attributed to an isotopic mass effect on the rotational axes which influences non-adiabatic coupling strengths. in addition, there is a population alternation with product rotational quantum number n for the oh/od(x, high nu, low n) product, most striking for the oh case, the sense of which is correlated with the value of the parent pseudo-quantum number k(a)(1). it is shown that this is a consequence of recoil forces which lead to a closing of the hod angle to near 90 degrees accompanying non-adiabatic transfer from the (c) over tilde state to the (a) over tilde((1)b(1)) state. the oscillation in population then derives from the symmetry properties around this angle of the product rotational wavefunctions. this suggests that the symmetry-induced population oscillation can only occur for a narrowly defined angular dissociation path. model calculations also explain the different structure of the spin-orbit doubled low n band heads for each nu(oh/od) which also alternates for even and odd k(a)(1). the necessary conditions to observe these phenomena are discussed. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | state dynamical picture ; absorption-band ; lambda-doublet ; 121.6 nm ; photodissociation ; h2o ; oh ; photofragmentation ; distributions ; pathways |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000278110600009 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142192]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Lina,Yuan, Kaijun,Cheng, Yuan,et al. Product rotational Franck-Condon oscillations in HOD (Jka,kc) dissociation[J]. molecular physics,2010,108(7-9):905-914. |
| APA | Cheng, Lina,Yuan, Kaijun,Cheng, Yuan,Guo, Qing,Yang, Xueming,&Dixon, Richard N..(2010).Product rotational Franck-Condon oscillations in HOD (Jka,kc) dissociation.molecular physics,108(7-9),905-914. |
| MLA | Cheng, Lina,et al."Product rotational Franck-Condon oscillations in HOD (Jka,kc) dissociation".molecular physics 108.7-9(2010):905-914. |
入库方式： OAI收割
来源：大连化学物理研究所
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