中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effects of Ce/Zr ratio on the structure and performances of Co-Ce1-xZrxO2 catalysts for carbon dioxide reforming of methane

文献类型:期刊论文

作者Wang, Ning1,2; Chu, Wei1; Huang, Liqiong1; Zhang, Tao3
刊名journal of natural gas chemistry
出版日期2010-03-01
卷号19期号:2页码:117-122
关键词Ce1-xZrxO2 carbon dioxide methane dry reforming Co-incorporated catalyst characterization
英文摘要the co-mcorporated ce1-xzrxo2 catalysts were prepared by co-precipitation for carbon dioxide reforming of methane the ratio of cc to zr was varied to optimize the performances of co-precipitated co-cc-zr-x, catalysts the prepared catalysts were characterized by various physico-chemical characterization techniques including tp12. x-ray diffraction, n-2 adsorption at low temperature. xps and co2-tpsr the co-precipitated ce1-xzrxo2 202 sample containing 16% co0 exhibited a higher catalytic activity among the five catalysts. and the activity was maintained without siumlicant loss during the reaction for 60 h under the conditions of 750 c, 0 i mpa. 36000 mllil gcm). and co2/c1-14 molar ratio of 1 i. the co, conversion over this catalyst was 75% while the ci-14 conversion was 67% the cubic ceo szro 202 facilitated a higher dispersion and a highel reducibility of the cobalt component. and the apparent activation energy fol co-ceo szro 207 sample was 49 1 kj/mol in the co2/ch4 reforming reaction as a result. the co-ceo szro 202 sample exhibited a higher activity and stability for the reforming of ch4 with co2
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical
研究领域[WOS]chemistry ; energy & fuels ; engineering
关键词[WOS]glow-discharge plasma ; fischer-tropsch synthesis ; solid-solution catalysts ; ni/gamma-al2o3 catalysts ; cobalt catalysts ; co2 ; ch4 ; deposition ; zirconia ; support
收录类别SCI
语种英语
WOS记录号WOS:000276957700003
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/142194]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Sichuan Univ, Dept Chem Engn, Chengdu 610065, Sichuan, Peoples R China
2.Sichuan Univ, Dept Architecture & Environm, Chengdu 610065, Sichuan, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Wang, Ning,Chu, Wei,Huang, Liqiong,et al. Effects of Ce/Zr ratio on the structure and performances of Co-Ce1-xZrxO2 catalysts for carbon dioxide reforming of methane[J]. journal of natural gas chemistry,2010,19(2):117-122.
APA Wang, Ning,Chu, Wei,Huang, Liqiong,&Zhang, Tao.(2010).Effects of Ce/Zr ratio on the structure and performances of Co-Ce1-xZrxO2 catalysts for carbon dioxide reforming of methane.journal of natural gas chemistry,19(2),117-122.
MLA Wang, Ning,et al."Effects of Ce/Zr ratio on the structure and performances of Co-Ce1-xZrxO2 catalysts for carbon dioxide reforming of methane".journal of natural gas chemistry 19.2(2010):117-122.

入库方式: OAI收割

来源:大连化学物理研究所

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