Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24]
文献类型：期刊论文
| 作者 | Lue, Hongying1; Zhang, Yongna2; Jiang, Zongxuan2; Li, Can2 |
| 刊名 | green chemistry
 |
| 出版日期 | 2010 |
| 卷号 | 12期号:11页码:1954-1958 |
| 英文摘要 | benzothiophene (bt), dibenzothiophene (dbt) and 4,6-dimethyldibenzothiophene (4,6-dmdbt) are oxidized to their corresponding sulfones by an anderson-type catalyst [(c18h37)(2)n(ch3)(2)](5)imo6o24 using molecular oxygen as the oxidant under mild reaction conditions. these refractory sulfur-containing compounds can be oxidized completely in the absence of any sacrificial agent. solvents such as acetonitrile and water play a negative effect on the oxidative desulfurization system. the catalytic activities of the amphiphilic anderson catalysts depend on the quaternary ammonium cations. the reactivity of the sulfur-containing compounds follows the order 4,6-dmdbt > dbt > bt. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | ultra-deep desulfurization ; selective oxidation ; molecular-oxygen ; chemical oxidation ; emulsion droplets ; hydrogen-peroxide ; diesel fuel ; acid ; hexamolybdochromate(iii) ; extraction |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000283936800012 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142195]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Yantai Univ, Sci & Engn Coll Chem & Biol, Yantai 264005, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lue, Hongying,Zhang, Yongna,Jiang, Zongxuan,et al. Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24][J]. green chemistry,2010,12(11):1954-1958. |
| APA | Lue, Hongying,Zhang, Yongna,Jiang, Zongxuan,&Li, Can.(2010).Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24].green chemistry,12(11),1954-1958. |
| MLA | Lue, Hongying,et al."Aerobic oxidative desulfurization of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene using an Anderson-type catalyst [(C18H37)(2)N(CH3)(2)](5)[IMo6O24]".green chemistry 12.11(2010):1954-1958. |
入库方式： OAI收割
来源：大连化学物理研究所
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