Studies on heat capacities and thermal analysis of Li-Mg-N-H hydrogen storage system
文献类型：期刊论文
| 作者 | Xu, F.2; Sun, L. X.1; Chen, P.1; Qi, Y. N.1; Zhang, J.1; Zhao, J. N.1; Liu, Y. F.3; Zhang, L.4; Cao, Zhong4; Yang, D. W.4 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2010-05-01 |
| 卷号 | 100期号:2页码:701-706 |
| 关键词 | Li-Mg-N-H system MDSC Heat capacity TG |
| 英文摘要 | the heat capacities of linh2 and li2mgn2h2 were measured by a modulated differential scanning calorimetry (mdsc) over the temperature range from 223 to 473 k for the first time. the value of heat capacity of linh2 is bigger than that of li2mgn2h2 from 223 to 473 k. the thermodynamic parameters such as enthalpy (h-h (298.15)) and entropy (s-s (298.15)) versus 298.15 k were calculated based on the above heat capacities. the thermal stabilities of them were investigated by thermogravimetric analysis (tg) at a heating rate of 10 k min(-1) with ar gas flow rate of 30 ml min(-1) from room temperature to 1,080 k. tg curves showed that the thermal decomposition of them occurred in two stages. the order of thermal stability of them is: li2mgn2h2 > linh2. the results indicate that addition of mg increases the thermal stability of li-n-h system and decrease the value of heat capacities of li-n-h system. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | differential scanning calorimetry ; thermodynamic properties ; imides ; dsc |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000276771600043 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142204]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Liaoning Normal Univ, Coll Chem & Chem Engn, Dalian 116029, Peoples R China 3.Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China 4.Changsha Univ Sci & Technol, Sch Chem & Environm Engn, Changsha 410076, Hunan, Peoples R China 5.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, F.,Sun, L. X.,Chen, P.,et al. Studies on heat capacities and thermal analysis of Li-Mg-N-H hydrogen storage system[J]. journal of thermal analysis and calorimetry,2010,100(2):701-706. |
| APA | Xu, F..,Sun, L. X..,Chen, P..,Qi, Y. N..,Zhang, J..,...&Du, Y..(2010).Studies on heat capacities and thermal analysis of Li-Mg-N-H hydrogen storage system.journal of thermal analysis and calorimetry,100(2),701-706. |
| MLA | Xu, F.,et al."Studies on heat capacities and thermal analysis of Li-Mg-N-H hydrogen storage system".journal of thermal analysis and calorimetry 100.2(2010):701-706. |
入库方式： OAI收割
来源：大连化学物理研究所
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