Thermodynamic Studies of Rod- and Spindle-Shaped beta-FeOOH Crystals
文献类型:期刊论文
作者 | Wei, Chengzhen1; Wang, Xiaoming1; Nan, Zhaodong1; Tan, Zhicheng2 |
刊名 | journal of chemical and engineering data
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出版日期 | 2010 |
卷号 | 55期号:1页码:366-369 |
英文摘要 | different morphologies of beta-feooh including rod- and spindle-shaped crystals were synthesized via a hydrothermal reaction at low temperature. the molar heat capacities of the obtained samples were determined by a precision automated adiabatic calorimeter over the temperature range of (78 to 390) k. the observed results demonstrated that the change of the molar heat capacity with thermodynamic temperature was different for the rod and spindle-shaped beta-feooh crystals. polynomial equations of the molar heat capacities as a function of temperature were fitted by a least-squares method for the rod- and spindle-shaped beta-feooh crystals. smoothed heat capacities and thermodynamic functions of the obtained samples, such as h(t/k) - h(298.15) and s(t/k) - s(298.15), were calculated on the basis of the fitted polynomials and the relationships of the thermodynamic functions. in addition, the as-prepared samples were also characterized by x-ray powder diffraction (xrd), transmission electron microscopy (tem), and thermal gravimetric analysis (tga). |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, multidisciplinary ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | alpha-fe2o3 nanorods ; enthalpy |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000273405200056 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/142228] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Wei, Chengzhen,Wang, Xiaoming,Nan, Zhaodong,et al. Thermodynamic Studies of Rod- and Spindle-Shaped beta-FeOOH Crystals[J]. journal of chemical and engineering data,2010,55(1):366-369. |
APA | Wei, Chengzhen,Wang, Xiaoming,Nan, Zhaodong,&Tan, Zhicheng.(2010).Thermodynamic Studies of Rod- and Spindle-Shaped beta-FeOOH Crystals.journal of chemical and engineering data,55(1),366-369. |
MLA | Wei, Chengzhen,et al."Thermodynamic Studies of Rod- and Spindle-Shaped beta-FeOOH Crystals".journal of chemical and engineering data 55.1(2010):366-369. |
入库方式: OAI收割
来源:大连化学物理研究所
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