Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen
文献类型：期刊论文
| 作者 | Sheng, Xuebin1,2; Ma, Hong1; Chen, Chen1; Gao, Jin1; Yin, Guochuan3; Xu, Jie1 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2010-09-25 |
| 卷号 | 11期号:15页码:1189-1192 |
| 关键词 | Alcohol oxidation Dioxygen Cyclic voltammetry Nitrosonium cation |
| 英文摘要 | efficient transformation of alcohols to the corresponding aldehydes is an important process in organic synthesis and industry. in the absence of transition metal ion, an acid-activated nox has been explored for the catalytic oxidation of benzyl alcohol. under the optimal conditions, 95% yield of benzyl aldehyde could be achieved at room temperature with dioxygen as the terminal oxidant. the reaction mechanism was investigated through uv-visible spectrometry and cyclic voltammetry, and the key active species for oxidation have been assigned to the nitrosonium cation. (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | transition-metal-free ; mild conditions ; nitric-oxide ; heterogeneous system ; molecular-oxygen ; nitrogen-oxides ; electrodes ; 1,4-dihydropyridines ; reduction ; sulfate |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000282154200006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142255]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Huazhong Univ Sci & Technol, Sch Chem & Chem Engn, Wuhan 430074, Peoples R China |
| 推荐引用方式 GB/T 7714 | Sheng, Xuebin,Ma, Hong,Chen, Chen,et al. Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen[J]. catalysis communications,2010,11(15):1189-1192. |
| APA | Sheng, Xuebin,Ma, Hong,Chen, Chen,Gao, Jin,Yin, Guochuan,&Xu, Jie.(2010).Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen.catalysis communications,11(15),1189-1192. |
| MLA | Sheng, Xuebin,et al."Acid-assisted catalytic oxidation of benzyl alcohol by NOx with dioxygen".catalysis communications 11.15(2010):1189-1192. |
入库方式： OAI收割
来源：大连化学物理研究所
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