Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene
文献类型：期刊论文
| 作者 | Xiao, Chong-fa; Shen, Guan-lin; Wang, Xiu-yan; Yang, Xue-ming |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2010-12-01 |
| 卷号 | 23期号:6页码:621-625 |
| 关键词 | Fluorine atom 1 S(N)2 mechanism Universal crossed molecular beam 2-Butadiene |
| 英文摘要 | we have investigated the dynamics of the f+c4h6 reaction using the universal crossed molecular beam method. the c4h5f+h reaction channel was observed in this experiment. angular resolved time-of-flight spectra have been measured for the c4h5f product. product angular distributions as well as kinetic energy distributions were determined for this product channel. experimental results show that the c4h5f product is largely backward scattered with considerable forward scattering signal, relative to the f atom beam direction. this suggests that the reaction channel mainly proceeds via a long-lived complex formation mechanism, with possible contribution from a direct s(n)2 type mechanism. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | molecular-beam ; scattering dynamics ; f+cd4 reaction ; shock-tube ; ab-initio ; 193 nm ; decomposition ; photochemistry ; isomers ; photodissociation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000286298900001 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142269]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Chong-fa,Shen, Guan-lin,Wang, Xiu-yan,et al. Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene[J]. chinese journal of chemical physics,2010,23(6):621-625. |
| APA | Xiao, Chong-fa,Shen, Guan-lin,Wang, Xiu-yan,&Yang, Xue-ming.(2010).Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene.chinese journal of chemical physics,23(6),621-625. |
| MLA | Xiao, Chong-fa,et al."Crossed Beams Study on the Dynamics of F Atom Reaction with 1,2-Butadiene".chinese journal of chemical physics 23.6(2010):621-625. |
入库方式： OAI收割
来源：大连化学物理研究所
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