Thermodynamic properties and heat capacities of Co (BTC)(1/3) (DMF) (HCOO)
文献类型：期刊论文
| 作者 | Jiang, Chun-Hong2,3; Song, Li-Fang2,3; Zhang, Jian2; Sun, Li-Xian2; Xu, Fen1; Li, Fen2; Jiao, Qing-Zhu1; Sun, Zhen-Gang1; Xing, Yong-Heng1; Du, Yong4 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2010-12-01 |
| 卷号 | 102期号:3页码:1087-1093 |
| 关键词 | Apparent activation energy Co MDSC Molar heat capacity Metal organic frameworks TG |
| 英文摘要 | a novel metal organic framework [co (btc)(1/3) (dmf) (hcoo)] (n) (comof, btc = 1,3,5-benzene tricarboxylate, dmf = n,n-dimethylformamide) has been synthesized solvothermally and characterized by single crystal x-ray diffraction, x-ray powder diffraction, and ft-ir spectra. the molar heat capacity of the compound was measured by modulated differential scanning calorimetry (mdsc) over the temperature range from 198 to 418 k for the first time. the thermodynamic parameters such as entropy and enthalpy versus 298.15 k based on the above molar heat capacity were calculated. moreover, a four-step sequential thermal decomposition mechanism for the comof was investigated through the thermogravimetry and mass spectrometer analysis (tg-dtg-ms) from 300 to 800 k. the apparent activation energy of the first decomposition step of the compound was calculated by the kissinger method using experimental data of tg analysis. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic framework ; coordination polymers ; sorption properties ; kinetics ; h-2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000284433000035 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142272]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China 5.Changsha Univ Sci & Technol, Sch Chem & Environm Engn, Changsha 410076, Hunan, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jiang, Chun-Hong,Song, Li-Fang,Zhang, Jian,et al. Thermodynamic properties and heat capacities of Co (BTC)(1/3) (DMF) (HCOO)[J]. journal of thermal analysis and calorimetry,2010,102(3):1087-1093. |
| APA | Jiang, Chun-Hong.,Song, Li-Fang.,Zhang, Jian.,Sun, Li-Xian.,Xu, Fen.,...&Cao, Zhong.(2010).Thermodynamic properties and heat capacities of Co (BTC)(1/3) (DMF) (HCOO).journal of thermal analysis and calorimetry,102(3),1087-1093. |
| MLA | Jiang, Chun-Hong,et al."Thermodynamic properties and heat capacities of Co (BTC)(1/3) (DMF) (HCOO)".journal of thermal analysis and calorimetry 102.3(2010):1087-1093. |
入库方式： OAI收割
来源：大连化学物理研究所
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