Efficient Conversion of Furfuryl Alcohol into Alkyl Levulinates Catalyzed by an Organic-Inorganic Hybrid Solid Acid Catalyst
文献类型：期刊论文
| 作者 | Zhang, Zehui1,3; Dong, Kun1,3; Zhao, Zongbao (Kent)1,2 |
| 刊名 | chemsuschem
 |
| 出版日期 | 2011 |
| 卷号 | 4期号:1页码:112-118 |
| 关键词 | alcohols biomass heterogeneous catalysis solvolysis sustainable chemistry |
| 英文摘要 | a clean, facile, and environment-friendly catalytic method has been developed for the conversion of furfuryl alcohol into alkyl levulinates making use of the novel solid catalyst methylimidazolebutylsulfate phosphotungstate ([mimbs](3)pw(12)o(40)). the solid catalyst is an organic-inorganic hybrid material, which consists of an organic cation and an inorganic anion. a study for optimizing the reaction conditions such as the reaction time, the temperature and the catalyst loading has been performed. under optimal conditions, a high n-butyl levulinate yield of up to 93% is obtained. furthermore, the kinetics of the reaction pathways and the mechanism for the alcoholysis of furfuryl alcohol are discussed. this method is environmentally benign and economical for the conversion of biomass-based derivatives into fine chemicals. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | selective hydrogenation ; ethyl levulinate ; transesterification ; polymerization ; esterification ; complexes ; cellulose ; kinetics ; phase ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287138900018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142307]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.CAS, Dalian Inst Chem Phys, Dalian, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Zehui,Dong, Kun,Zhao, Zongbao . Efficient Conversion of Furfuryl Alcohol into Alkyl Levulinates Catalyzed by an Organic-Inorganic Hybrid Solid Acid Catalyst[J]. chemsuschem,2011,4(1):112-118. |
| APA | Zhang, Zehui,Dong, Kun,&Zhao, Zongbao .(2011).Efficient Conversion of Furfuryl Alcohol into Alkyl Levulinates Catalyzed by an Organic-Inorganic Hybrid Solid Acid Catalyst.chemsuschem,4(1),112-118. |
| MLA | Zhang, Zehui,et al."Efficient Conversion of Furfuryl Alcohol into Alkyl Levulinates Catalyzed by an Organic-Inorganic Hybrid Solid Acid Catalyst".chemsuschem 4.1(2011):112-118. |
入库方式： OAI收割
来源：大连化学物理研究所
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