Oxidative Coupling of NH Isoquinolones with Olefins Catalyzed by Rh(III)
文献类型：期刊论文
| 作者 | Wang, Fen1,2; Song, Guoyong2; Du, Zhengyin1; Li, Xingwei2 |
| 刊名 | journal of organic chemistry
 |
| 出版日期 | 2011-04-15 |
| 卷号 | 76期号:8页码:2926-2932 |
| 英文摘要 | rh(iii)-catalyzed oxidative coupling reactions between isoquinolones with 3-aryl groups and activated olefins have been achieved using anhydrous cu(oac)(2) as an oxidant to give tetracyclic products. the nitrogen atom acts as a directing group to facilitate ortho c-h activation. this reaction can be one-pot starting from methyl benzohydroxamates, without the necessity of the isolation of isoquinolone products. abroad scope of substrates has been demonstrated, and both terminal and internal activated olefins can be applied. in the coupling of n-methylmaleimide, a wacker-like mechanism was proposed, where backside attack of the nh group in isoquinolones is suggested as a key step. selective c-h activation has also been achieved at the 8-position of 1-naphthol, leading to an olefination product. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | h bond-cleavage ; c-c ; activation reactions ; rhodium catalysis ; direct arylation ; alkynes ; functionalization ; alkenes ; arenes ; alkenylation |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000289187300062 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142310]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.NW Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Fen,Song, Guoyong,Du, Zhengyin,et al. Oxidative Coupling of NH Isoquinolones with Olefins Catalyzed by Rh(III)[J]. journal of organic chemistry,2011,76(8):2926-2932. |
| APA | Wang, Fen,Song, Guoyong,Du, Zhengyin,&Li, Xingwei.(2011).Oxidative Coupling of NH Isoquinolones with Olefins Catalyzed by Rh(III).journal of organic chemistry,76(8),2926-2932. |
| MLA | Wang, Fen,et al."Oxidative Coupling of NH Isoquinolones with Olefins Catalyzed by Rh(III)".journal of organic chemistry 76.8(2011):2926-2932. |
入库方式： OAI收割
来源：大连化学物理研究所
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