Ultrathin solid polymer electrolyte PEI/Pebax2533/AgBF4 composite membrane for propylene/propane separation
文献类型：期刊论文
| 作者 | Wang, Yanbei; Ren, Jizhong; Deng, Maicun |
| 刊名 | separation and purification technology
 |
| 出版日期 | 2011-02-02 |
| 卷号 | 77期号:1页码:46-52 |
| 关键词 | Carrier-facilitated transport Composite membrane Solid polymer electrolyte membrane Propylene/propane separation |
| 英文摘要 | in this paper, a new solid polymer electrolyte pei/pebax2533/agbf4 composite membrane (pei: polyetherimide; pebax2533: polynylon12/tetramethylene oxide block copolymer. pa12-ptmo) is prepared with complexing method. when the external surface of pebax2533 layer is immersed into agbf4 solution, silver salt transfers into pebax2533 layer according to the complexation with ether oxygens in pebax2533 backbone, and an ultrathin solid polymer electrolyte layer is formed. when agbf4 concentration is less than the threshold silver concentration c*(4.5 mol/l), because of low silver salt content in the solid polymer electrolyte layer, no carrier-facilitated transport phenomenon occurs. but for pei/pebax2533/agbf4 composite membrane prepared with agbf4 concentration above c*(4.5 mol/l), the percolation channels for carrier-facilitated transport are formed and the preferential adsorbed propylene molecules can transfer across the membrane easily, which result in an increase of propylene permeance and a sharp decrease of propane permeance. according to tem observation, an ultrathin solid polymer electrolyte layer of 100-200 nm thickness exists in the external surface of the pebax2533 layer of pei/pebax2533/agbf4 composite membrane. (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology |
| 类目[WOS] | engineering, chemical |
| 研究领域[WOS] | engineering |
| 关键词[WOS] | facilitated olefin transport ; silver ions ; olefin/paraffin separation ; polyimide membranes ; ethylene ; carrier ; salts |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287295900007 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142317]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Membrane Technol, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Yanbei,Ren, Jizhong,Deng, Maicun. Ultrathin solid polymer electrolyte PEI/Pebax2533/AgBF4 composite membrane for propylene/propane separation[J]. separation and purification technology,2011,77(1):46-52. |
| APA | Wang, Yanbei,Ren, Jizhong,&Deng, Maicun.(2011).Ultrathin solid polymer electrolyte PEI/Pebax2533/AgBF4 composite membrane for propylene/propane separation.separation and purification technology,77(1),46-52. |
| MLA | Wang, Yanbei,et al."Ultrathin solid polymer electrolyte PEI/Pebax2533/AgBF4 composite membrane for propylene/propane separation".separation and purification technology 77.1(2011):46-52. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。