A quasi-static method for measuring the deactivation rate constants of O-2(a(1)Delta(g)) in gas phase by IR radiation decay
文献类型：期刊论文
| 作者 | Du, Shuyan; Leng, Jing; Wang, Junhui; Yang, Heping; Sha, Guohe; Zhang, Cunhao |
| 刊名 | chemical physics letters
 |
| 出版日期 | 2011-03-10 |
| 卷号 | 504期号:4-6页码:241-244 |
| 英文摘要 | a quasi-static method is developed for measuring the deactivation rate constants of o-2(a(1)delta(g)) in gas phase by monitoring its ir radiation decay via a flow-stop technique. this method has taken into account the energy-pooling reaction of o-2(a(1)delta) and thus suits fairly high o-2(a(1)delta) concentration without identifying its absolute value, leading to simpler operation and higher signal/noise ratio. utilizing this method, the o-2(a(1)delta) deactivation rate by d2o is for the first time measured to be 2.10 +/- 0.18 x 10 (18) cm(3) s (1), while those for o-2(x-3 sigma(-)(g)), h2o, h-2 and d-2 are found to agree well with the data in literature. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | singlet molecular-oxygen ; co2 ; o2(a1-delta-g) ; o2(a1deltag) ; excitation ; mechanisms |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000288024000027 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142318]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Shuyan,Leng, Jing,Wang, Junhui,et al. A quasi-static method for measuring the deactivation rate constants of O-2(a(1)Delta(g)) in gas phase by IR radiation decay[J]. chemical physics letters,2011,504(4-6):241-244. |
| APA | Du, Shuyan,Leng, Jing,Wang, Junhui,Yang, Heping,Sha, Guohe,&Zhang, Cunhao.(2011).A quasi-static method for measuring the deactivation rate constants of O-2(a(1)Delta(g)) in gas phase by IR radiation decay.chemical physics letters,504(4-6),241-244. |
| MLA | Du, Shuyan,et al."A quasi-static method for measuring the deactivation rate constants of O-2(a(1)Delta(g)) in gas phase by IR radiation decay".chemical physics letters 504.4-6(2011):241-244. |
入库方式： OAI收割
来源：大连化学物理研究所
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